Journal ArticleDOI
Dicarboxylic acid esters from the carbonylation of unsaturated esters under mild conditions
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TLDR
The methoxycarbonylation of unsaturated acids or esters catalysed by Pd complexes of bis(ditertiarybutyl-phosphinomethyl)benzene (DTBPMB) produces α,ω-diesters with selectivities >95%, even if the double bond is deep in the chain or conjugated to the carbonyl group.About:
This article is published in Inorganic Chemistry Communications.The article was published on 2005-10-01. It has received 153 citations till now. The article focuses on the topics: Carbonylation & Dicarboxylic acid.read more
Citations
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Oils and Fats as Renewable Raw Materials in Chemistry
TL;DR: The remarkable advances made during the last decade in organic synthesis, catalysis, and biotechnology using plant oils and the basic oleochemicals derived from them will be reported, including, for example, ω-functionalization of fatty acids containing internal double bonds, application of the olefin metathesis reaction, and de novo synthesis of fatty fatty acids from abundantly available renewable carbon sources.
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Plant oils: The perfect renewable resource for polymer science?!
TL;DR: In this paper, the authors provide an overview of the present situation with special attention to the use of olefin metathesis and thiol-ene chemistry as synthetic methods and as polymerization techniques.
Journal ArticleDOI
Palladium-Catalyzed Carbonylation Reactions of Alkenes and Alkynes
TL;DR: In this paper, the authors summarize the recent catalyst developments and selected organic applications in this area and present a plethora of palladium catalysts and various synthetic protocols are available for the synthesis of valuable carboxylic acids and acrylic acids as well as their derivatives.
Journal ArticleDOI
Homogeneous catalysis for the conversion of biomass and biomass-derived platform chemicals
TL;DR: In this article, the authors provide an overview of the most important recent developments in homogeneous catalysis towards the production and transformation of biomass and biomass related model compounds, including the chemical valorisation of the main components of lignocellulosic biomass.
Journal ArticleDOI
Renewability is not Enough: Recent Advances in the Sustainable Synthesis of Biomass-Derived Monomers and Polymers
Audrey Llevot,Patrick-Kurt Dannecker,Marc von Czapiewski,Lena Charlotte Over,Zafer Söyler,Michael A. R. Meier +5 more
TL;DR: The chemistry of vegetable oil derivatives, terpenes, lignin, carbohydrates, and sugar-based platform chemicals was selected to highlight the trends in the active field of a sustainable use of renewable resources.
References
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BookDOI
Applied Homogeneous Catalysis with Organometallic Compounds
Boy Cornils,Wolfgang A. Herrmann +1 more
Journal ArticleDOI
Highly selective formation of linear esters from terminal and internal alkenes catalysed by palladium complexes of bis-(di-tert-butylphosphinomethyl)benzene
TL;DR: The methoxycarbonylation of terminal or internal alkenes catalysed by palladium complexes of bis-(di-tert-butylphosphinomethyl)benzene under mild conditions leads to linear esters in 99% selectivity via a hydride mechanism.
Journal ArticleDOI
Catalytic Metathesis of Unsaturated Fatty Acid Esters and Oils
TL;DR: In this paper, the authors describe the catalytic routes that are available for converting unsaturated fatty acid esters and related compounds, obtained from renewable resources, into useful chemical products via the olefin metathesis reaction.
Journal ArticleDOI
Oxygenation cascade in conversion of n-alkanes to alpha,omega-dioic acids catalyzed by cytochrome P450 52A3.
TL;DR: It is demonstrated that a single P450 form is able to efficiently catalyze a cascade of sequential mono- and diterminal monooxygenation reactions from n-alkanes to α,ω-dioic acids with high regioselectivity.
Journal ArticleDOI
Catalytic carboxylation of fats. Carboxy acids and esters from monounsaturates
E. N. Frankel,F. L. Thomas +1 more
TL;DR: In this article, a highly selective catalytic, one-step synthesis of oleic acid into 9(10)-carboxystearic acid in high yields is described.