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Dye-sensitized Solar Cells
TLDR
The dye-sensitized solar cells (DSC) as discussed by the authors provides a technically and economically credible alternative concept to present day p-n junction photovoltaic devices, where light is absorbed by a sensitizer, which is anchored to the surface of a wide band semiconductor.Abstract:
The dye-sensitized solar cells (DSC) provides a technically and economically credible alternative concept to present day p–n junction photovoltaic devices. In contrast to the conventional systems where the semiconductor assume both the task of light absorption and charge carrier transport the two functions are separated here. Light is absorbed by a sensitizer, which is anchored to the surface of a wide band semiconductor. Charge separation takes place at the interface via photo-induced electron injection from the dye into the conduction band of the solid. Carriers are transported in the conduction band of the semiconductor to the charge collector. The use of sensitizers having a broad absorption band in conjunction with oxide films of nanocrstalline morphology permits to harvest a large fraction of sunlight. Nearly quantitative conversion of incident photon into electric current is achieved over a large spectral range extending from the UV to the near IR region. Overall solar (standard AM 1.5) to current conversion efficiencies (IPCE) over 10% have been reached. There are good prospects to produce these cells at lower cost than conventional devices. Here we present the current state of the field, discuss new concepts of the dye-sensitized nanocrystalline solar cell (DSC) including heterojunction variants and analyze the perspectives for the future development of the technology.read more
Citations
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Applications of ionic liquids in the chemical industry
TL;DR: There have been parallel and collaborative exchanges between academic research and industrial developments since the materials were first reported in 1914, it is demonstrated.
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Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers
Simon Mathew,Aswani Yella,Peng Gao,Robin Humphry-Baker,Basile F. E. Curchod,Negar Ashari-Astani,Ivano Tavernelli,Ursula Rothlisberger,Md. K. Nazeeruddin,Michael Grätzel +9 more
TL;DR: A molecularly engineered porphyrin dye is reported, coded SM315, which features the prototypical structure of a donor-π-bridge-acceptor and both maximizes electrolyte compatibility and improves light-harvesting properties.
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TiO2 nanotubes: synthesis and applications.
TL;DR: This review attempts to cover all aspects, including underlying principles and key functional features of TiO(2), in a comprehensive way and also indicates potential future directions of the field.
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Metal-Free Organic Dyes for Dye-Sensitized Solar Cells: From Structure: Property Relationships to Design Rules
TL;DR: Recent advances in molecular design and technological aspects of metal-free organic dyes for applications in dye-sensitized solar cells are focused on.
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Electrochemical Impedance Spectroscopic Analysis of Dye-Sensitized Solar Cells
TL;DR: The EIS measurements show that DSC performance variations under prolonged thermal aging result mainly from the decrease in the lifetime of the conduction band electron in the TiO2 film.
References
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A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films
TL;DR: In this article, the authors describe a photovoltaic cell, created from low-to medium-purity materials through low-cost processes, which exhibits a commercially realistic energy-conversion efficiency.
Journal Article
Photoelectrochemical cells : Materials for clean energy
TL;DR: In this paper, the authors look into the historical background, and present status and development prospects for photoelectrochemical cells, based on nanocrystalline materials and conducting polymer films.
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Conversion of light to electricity by cis-X2bis(2,2'-bipyridyl-4,4'-dicarboxylate)ruthenium(II) charge-transfer sensitizers (X = Cl-, Br-, I-, CN-, and SCN-) on nanocrystalline titanium dioxide electrodes
Mohammad Khaja Nazeeruddin,Andreas Kay,I. Rodicio,Robin Humphry-Baker,E. Mueller,Paul Liska,Nick Vlachopoulos,Michael Graetzel +7 more
TL;DR: Cis-X 2 Bis(2,2'-bipyridyl-4,4'-dicarboxylate)ruthenium(II) complexes were prepared and characterized with respct to their absorption, luminescence, and redox behavior.
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Hybrid Nanorod-Polymer Solar Cells
TL;DR: It is demonstrated that semiconductor nanorods can be used to fabricate readily processed and efficient hybrid solar cells together with polymers and Tuning the band gap by altering the nanorod radius enabled us to optimize the overlap between the absorption spectrum of the cell and the solar emission spectrum.
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Engineering of Efficient Panchromatic Sensitizers for Nanocrystalline TiO2-Based Solar Cells
Mohammad Khaja Nazeeruddin,Peter Pechy,Thierry Renouard,Shaik M. Zakeeruddin,Robin Humphry-Baker,Pascal Comte,Paul Liska,Le Cevey,E Costa,Valery Shklover,Leone Spiccia,Glen B. Deacon,Carlo Alberto Bignozzi,Michael Grätzel +13 more
TL;DR: The black dye, when anchored to nanocrystalline TiO(2) films achieves very efficient sensitization over the whole visible range extending into the near-IR region up to 920 nm, yielding over 80% incident photon-to-current efficiencies (IPCE).