Journal ArticleDOI
Effect of carbon atom pyramidalization on the bonding in ethylene
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This article is published in Journal of the American Chemical Society.The article was published on 1979-01-01. It has received 39 citations till now. The article focuses on the topics: Ethylene.read more
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Cyclizations of Alkynes: Revisiting Baldwin’s Rules for Ring Closure
Kerry Gilmore,Igor V. Alabugin +1 more
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Palladium/Norbornene Cooperative Catalysis.
Jianchun Wang,Guangbin Dong +1 more
TL;DR: This Review provides a comprehensive overview of Palladium/norbornene cooperative catalysis, including the early stoichiometric investigations, catalytic reaction developments, as well as the applications in the syntheses of bioactive compounds and polymers.
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Rehybridization and π-orbital alignment: the key to the existence of spheroidal carbon clusters
TL;DR: In this article, the rehybridization and bonding in large carbon spheroids (C n ) with POAV/3D HMO theory was analyzed with the POAV-HMO theory.
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Silenes: Connectors between classical alkenes and nonclassical heavy alkenes
Henrik Ottosson,Anders M. Eklöf +1 more
TL;DR: In this article, the impact of substituents on the electronic and geometric structure, reactivity, and other properties of (formally) SiC double-bonded compounds is discussed.
Journal ArticleDOI
The Baldwin rules: revised and extended
TL;DR: The Baldwin rules constitute one of the clearest examples of the success which can be obtained through the application of stereoelectronic concepts to reaction design as mentioned in this paper, however, time has revealed a number of exceptions and gray areas within these rules, leading to extensions and revisions.