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Journal ArticleDOI

Effect of crosslinking on the mechanical and thermal properties of poly(vinyl alcohol)

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TLDR
In this article, a broad range of degrees of crosslinking, from 1.7 up to 74% of reacted hydroxyl groups, was achieved, and the variation of the thermal and mechanical properties of PVA with the crosslink density show an initial decrease due to the diminution of the crystallinity of the system, caused by the cross-linking.
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This article is published in Polymer.The article was published on 2000-12-15. It has received 480 citations till now. The article focuses on the topics: Vinyl alcohol & Hexamethylene diisocyanate.

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Citations
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Design, Synthesis and Study of Thermomechanically Active Polymer Networks Based on Latent Crosslinking of Semicrystalline Polymers

Wenbin Kuang
TL;DR: In this paper, the authors aim at design, fabrication, and characterization of novel crosslinkable semicrystalline polymeric materials utilizing different techniques and mechanisms in order to explore their special thermomechanical features as well as the possibilities for potential industrial application based on shape memory (SM) effects.
Proceedings ArticleDOI

Refill and Recharge Smart Portable Micro-Devices by Direct Methanol Fuel Cells: Developed with PVA Based Modified Electrolyte Membranes

TL;DR: In this paper, four types of Polyvinyl Alcohol (PVA) based membranes using the solution casting method for direct methanol fuel cells (DMFCs) application were presented, and the authors characterized the membranes by FTIR, water uptake, scanning electron microscopy (SEM) for surface morphology, ionic conductivity and fuel permeability.
Journal ArticleDOI

Hybrid zipper-like chitosan-carboxymethyl cellulose-ferric adsorbents for tunable anion adsorption

TL;DR: In this article , composites of carboxymethyl cellulose, chitosan, glutaraldehyde, and iron III species were characterized by FTIR, TGA, ICP-OES and SEM studies.
References
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Book

Encyclopedia of polymer science and engineering

TL;DR: In this paper, the authors describe a chain transfer characterisation of polymers charge-transfer complexes, charge transfer complexes and charge transfer complexes of charge transfer and charge-Transfer complexes.
Journal ArticleDOI

Effect of the morphology of hydrophilic polymeric matrices on the diffusion and release of water soluble drugs

TL;DR: In this article, drug release mechanisms from, and diffusion processes in hydrophilic crosslinked polymeric systems were investigated in two macromolecular states: in the glassy and rubbery states during the early part of countercurrent water diffusion, and in the rubbery state after thermodynamic equilibrium between the network and the surrounding dissolution medium (water) was attained.
Book

Polyvinyl alcohol : developments

C. A. Finch
TL;DR: Partial table of contents: Manufacture of polyvinyl Acetate for Polyvinyl Alcohol (F. Zvanut & F. ZVanut), hydrolysis ofPolyvinylAcetate to PolyvinYL Alcohol, and applications of Polyviny Alcohol in Adhesives and Applications of Polyvyl Alcohol as a Binder.
Journal ArticleDOI

Ferrogel: a new magneto-controlled elastic medium

TL;DR: In this paper, the influence of a non-uniform external magnetic field on the shape of gel tubes and the possibility to induce elongation and contraction by means of a magnetic field gradient produced by an electromagnet have been demonstrated.
Book ChapterDOI

Modification of Polymers

TL;DR: The early chemical efforts which lead to the modification of rubber via isomerization with acid (1781) or Vulcanization with sulfur (1839) were largely serendipitous discoveries as discussed by the authors.
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