Journal ArticleDOI
Effect of PEO addition on the electrolytic and thermal properties of PVDF-LiClO4 polymer electrolytes
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TLDR
In this paper, structural and ac-conductivity studies were performed to evaluate the ambient temperature conductivity of the polyvinylidene fluoride (PVDF) thin film membranes using XRD.About:
This article is published in Solid State Ionics.The article was published on 1997-12-11. It has received 198 citations till now. The article focuses on the topics: Conductivity & Electrolyte.read more
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Poly(ethylene oxide)-based electrolytes for lithium-ion batteries
Zhigang Xue,Dan He,Xiaolin Xie +2 more
TL;DR: In this article, a review of the recent developments and issues concerning polyethylene oxide (PEO) based electrolytes for lithium-ion batteries is presented, including blending, modifying and making PEO derivatives.
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Approaching Practically Accessible Solid-State Batteries: Stability Issues Related to Solid Electrolytes and Interfaces
TL;DR: This review presents an overview on the scientific challenges, fundamental mechanisms, and design strategies for solid-state batteries, specifically focusing on the stability issues ofSolid-state electrolytes and the associated interfaces with both cathode and anode electrodes.
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A conceptual review on polymer electrolytes and ion transport models
TL;DR: In this article, the authors provided a deep insight into the ion conduction mechanism in polymer electrolytes (PEs), and the relationship between impedance plots and equivalent circuits, which are crucial for electrical characterization, is extensively interpreted.
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Investigations on the effect of various plasticizers in PVA–PMMA solid polymer blend electrolytes
TL;DR: In this article, solid polymer electrolyte films containing poly(vinyl alcohol) (PVA)/PMMA-LiBF4-X (X=EC, PC, DEC, GBL) were prepared by solvent casting technique.
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Recent Advancements in Polymer-Based Composite Electrolytes for Rechargeable Lithium Batteries
TL;DR: A review of polymer-based composite electrolytes can be found in this article, where the benefits, synergistic mechanisms, design methods, and developments and outlooks for each individual composite strategy are explored.
References
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Enhanced lithium ion transport in PEO-based solid polymer electrolytes employing a novel class of plasticizers
TL;DR: In this paper, a novel class of esters of benzene 1,2 dicarboxylic acids such as DOP, dibutyl phthalate (DBP), and dimethyl phthalates (DMP) have been used as plasticizers in high molecular weight PEO-LiClO 4 matrix (PEO=poly(ethylene oxide)) to improve the room temperature ionic conductivity of polymer-salt complex.
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Conduction of lithium ions in polyvinylidene fluoride and its derivatives—I
TL;DR: In this article, a polymer solid electrolyte was prepared from the hybrid of poly(vinylidene fluoride) and lithium perchlorate, which was obtained as films having a thickness of about 0.1 mm and high lithium ionic conductivity.
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The effects of radiation-induced crosslinking on the conductance of LiClO4·PEO electrolytes
TL;DR: The conductance/temperature behavior of poly(ethylene oxide)/LiClO4 electrolyte prepared under anhydrous conditions has been studied in this article, where light crosslinking has been shown to cause a small reduction in the conductivity, probably due to restricted backbone segmental motion.
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The mechanism of lithium ion transport in polyacrylonitrile-based polymer electrolytes
TL;DR: In this article, a mechanism of Li+ ion transport in polyacrylonitrile (PAN)-based polymer electrolytes containing various plasticizers, has been suggested, which is mainly caused by the Li+ ions in the gel state.