Journal ArticleDOI
Enantiodifferentiating endo‐Selective Oxylactonization of ortho‐Alk‐1‐enylbenzoate with a Lactate‐Derived Aryl‐λ3‐Iodane
TLDR
In this article, the present protocol is applied to the synthesis of the naturally occurring aromatase inhibitor (VII) and it is shown that it can be applied to a variety of applications.Abstract:
The present protocol is applied to the synthesis of the naturally occurring aromatase inhibitor (VII).read more
Citations
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Journal ArticleDOI
Advances in Synthetic Applications of Hypervalent Iodine Compounds
TL;DR: One of the goals of this Review is to attract the attention of the scientific community as to the benefits of using hypervalent iodine compounds as an environmentally sustainable alternative to heavy metals.
Journal ArticleDOI
Enantioselective Metal‐Free Diamination of Styrenes
Journal ArticleDOI
Vicinal difunctionalization of alkenes with iodine(III) reagents and catalysts.
TL;DR: In this work, chiral non-racemic hypervalent iodine(III) reagents and catalysts have emerged as versatile tools for the realization of important enantioselective transformations in alkene difunctionalization reactions.
Journal ArticleDOI
Asymmetric dearomatizing spirolactonization of naphthols catalyzed by spirobiindane-based chiral hypervalent iodine species.
Toshifumi Dohi,Naoko Takenaga,Tomofumi Nakae,Yosuke Toyoda,Mikio Yamasaki,Motoo Shiro,Hiromichi Fujioka,Akinobu Maruyama,Yasuyuki Kita +8 more
TL;DR: A new series of ortho-functionalized spirobiindane catalysts are synthesized and demonstrated that the enantioselectivity can be dramatically improved by the presence of the substituents ortho to the iodine atom, which would contribute to estimation of the chiral hypervalent iodine compounds in asymmetric reactions.
Journal ArticleDOI
Copper-catalyzed olefinic trifluoromethylation of enamides at room temperature
TL;DR: Copper-catalyzed olefinic trifluoromethylation of enamides was reported in this paper. But this method was not suitable for the stereoselective synthesis of β-trifluorsomethyn substituted enamide.
References
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Journal ArticleDOI
Chemistry of Polyvalent Iodine
TL;DR: The present review summarizes the data that appeared in the literature following publication of previous reviews in 1996 and 2002 and is organized according to the classes of organic polyvalent iodine compounds with emphasis on their synthetic application.
Journal ArticleDOI
Hypervalent iodine chemistry in synthesis: scope and new directions.
TL;DR: This contribution summarizes recent achievements and highlights key findings and developments that will influence future research and lead to novel applications of hypervalent iodine reagents in synthesis.
Journal ArticleDOI
Hypervalent iodine reagents as a new entrance to organocatalysts
Toshifumi Dohi,Yasuyuki Kita +1 more
TL;DR: The historical background and the efforts made to realize the catalytic utilization of hypervalent iodine reagents are highlighted, especially with focus on iodine(iii).
Journal ArticleDOI
Hypervalent iodine-mediated oxidation of alcohols
Muhammet Uyanik,Kazuaki Ishihara +1 more
TL;DR: The design of hypervalent iodine catalysts is focused on and the discovery and development of the oxidation of alcohols with the stoichiometric or catalytic use of hyperValent iodine compounds is reviewed.
Related Papers (5)
Enantioselective Kita Oxidative Spirolactonization Catalyzed by In Situ Generated Chiral Hypervalent Iodine(III) Species
Highly stereoselective metal-free oxyaminations using chiral hypervalent iodine reagents
Umar Farid,Thomas Wirth +1 more