Journal ArticleDOI
Fe=B Double Bonds: Synthetic, Structural, and Reaction Chemistry of Cationic Terminal Borylene Complexes
TLDR
In this article, the role of steric bulk and π electron release within the ERn substituent in generating tractable borylene complexes has been probed, as has the nature of the counterion.About:
This article is published in Organometallics.The article was published on 2004-05-13. It has received 108 citations till now. The article focuses on the topics: Nucleophilic addition & Double bond.read more
Citations
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Journal ArticleDOI
Molecular Double-Bond Covalent Radii for Elements Li–E112
Pekka Pyykkö,Michiko Atsumi +1 more
TL;DR: The previous systems of triple-b Bond and single-bond self-consistent, additive covalent radii, R(AB)=r(A)+ r(B), are completed with a fit for sigma(2)pi(2).
Journal ArticleDOI
Electron-precise coordination modes of boron-centered ligands.
TL;DR: In this paper, Boryl Ligands et al. presented a new approach to solve the problem of homonymity in the context of cyber-bullying and cyber-attacks.
Journal ArticleDOI
Transition-metal complexes of boron-new insights and novel coordination modes.
TL;DR: The most useful synthetic strategies for the generation of transition-metal-boron bonds are highlighted here, and the most recent and intriguing compounds that have been reported are outlined and discussed.
Journal ArticleDOI
Borinium, borenium, and boronium ions : Synthesis, reactivity, and applications
TL;DR: It has been nearly 20 years since the last major review on boron cations and developments in weakly coordinating anion technology suggest that this area of research is ripe for exploration.
References
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Journal ArticleDOI
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density
TL;DR: Numerical calculations on a number of atoms, positive ions, and molecules, of both open- and closed-shell type, show that density-functional formulas for the correlation energy and correlation potential give correlation energies within a few percent.
Journal ArticleDOI
Density-functional exchange-energy approximation with correct asymptotic behavior.
TL;DR: This work reports a gradient-corrected exchange-energy functional, containing only one parameter, that fits the exact Hartree-Fock exchange energies of a wide variety of atomic systems with remarkable accuracy, surpassing the performance of previous functionals containing two parameters or more.
Journal ArticleDOI
Chemistry with ADF
G. te Velde,F.M. Bickelhaupt,Evert Jan Baerends,C. Fonseca Guerra,S. J. A. van Gisbergen,J.G. Snijders,T. Ziegler +6 more
TL;DR: The “Activation‐strain TS interaction” (ATS) model of chemical reactivity is reviewed as a conceptual framework for understanding how activation barriers of various types of reaction mechanisms arise and how they may be controlled, for example, in organic chemistry or homogeneous catalysis.
Journal ArticleDOI
The nature of .pi.-.pi. interactions
Related Papers (5)
Transition metal boryl and borylene complexes: substitution and abstraction chemistry
Simon Aldridge,Deborah L. Coombs +1 more