Journal ArticleDOI
Ferroelectric Tungsten Bronze‐Type Crystal Structures. I. Barium Strontium Niobate Ba0.27Sr0.75Nb2O5.78
TLDR
The Ferroelectric Ba0.27Sr0.75Nb2O5.78 as discussed by the authors is a tungsten bronze-type structure crystallizing in the tetragonal system, with lattice constants a = 12.43024Abstract:
Ferroelectric Ba0.27Sr0.75Nb2O5.78, with Tc = 348° ± 15°K, is a tungsten bronze‐type structure crystallizing in the tetragonal system, with lattice constants a = 12.43024 ± 0.00002 and c = 3.91341 ± 0.00001 A at 298°K, space group P4bm, and five formulas in the unit cell. The integrated intensities of 6781 structure factors were measured with PEXRAD, 875 symmetry‐independent structure factors being significantly above background. The metal‐atom positions were determined from the three‐dimensional Patterson function and the oxygen atoms from subsequent Fourier series. The final agreement factor between measured and calculated structure factors is 0.0508. The structure consists of close‐packed slightly puckered layers of oxygen atoms separated by nearly c / 2. The Nb atoms are slightly displaced from one layer, the Ba and Sr atoms from the other and in the same sense. The oxygen atoms in the Ba and Sr layer are disordered. Neither of the two independent sites occupied by the Ba and Sr atoms is fully filled....read more
Citations
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Perspective on the Development of Lead-free Piezoceramics
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Pyroelectric devices and materials
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Oxygen‐Octahedra Ferroelectrics. I. Theory of Electro‐optical and Nonlinear optical Effects
M. DrDomenico,S. H. Wemple +1 more
TL;DR: In this article, a microscopic tensor theory of the electro-optical and nonlinear optical effects in oxygen-octahedra ferroelectrics is presented, which stresses the importance of the basic BO6 octahedron building block in this class of materials.
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Lead-Free Relaxor Ferroelectrics
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Investigation of the Electrical Properties of Sr1−xBaxNb2O6 with Special Reference to Pyroelectric Detection
TL;DR: In this paper, the dielectric constants, electrical conductivity, specific heat, and pyroelectric coefficients of ferroelectric Sr1−xBaxNb2O6 (SBN) were investigated as a function of temperature in the range 10°-500°K, and as a result of the Sr/Ba composition of the material.
References
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Book
International tables for X-ray crystallography
Norman Fordyce McKerron Henry,Lonsdale, Kathleen, Dame,John S. Kasper,Caroline H. MacGillavry,Gerard D. Rieck,James A. Ibers,Walter C. Hamilton +6 more
Journal ArticleDOI
Anomalous dispersion corrections computed from self-consistent field relativistic Dirac–Slater wave functions
Journal ArticleDOI
The secondary extinction correction
TL;DR: In this article, it was shown that Darwin's formula for the secondary extinction correction, which has been universally accepted and extensively used, contains an appreciable error in the x-ray diffraction case.
Journal ArticleDOI
Electro‐optic coefficients of ferroelectric strontium barium niobate
TL;DR: In this article, the system of ferroelectric strontium barium niobates, SrxBa1•xNb2O6, was investigated and linear electrooptic coefficients as large as r ∼ 4 × 10−5 cm/statvolt have been measured.