Journal ArticleDOI
Fine Tuning the Energetics of Excited-State Intramolecular Proton Transfer (ESIPT): White Light Generation in A Single ESIPT System
Kuo-Chun Tang,Ming-Jen Chang,Tsung-Yi Lin,Hsiao-An Pan,Tzu-Chien Fang,Kew-Yu Chen,Wen-Yi Hung,Yu-Hsiang Hsu,Pi-Tai Chou +8 more
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TLDR
The results provide the proof of concept that the white light generation can be achieved in a single ESIPT system.Abstract:
Using 7-hydroxy-1-indanone as a prototype (I), which exhibits excited-state intramolecular proton transfer (ESIPT), chemical modification has been performed at C(2)-C(3) positions by fusing benzene (molecule II) and naphthalene rings, (molecule III) I undergoes an ultrafast rate of ESIPT, resulting in a unique tautomer emission (λ(max) ∼530 nm), whereas excited-state equilibrium is established for both II and III, as supported by the dual emission and the associated relaxation dynamics The forward ESIPT (normal to proton-transfer tautomer species) rates for II and III are deduced to be (30 ps)(-1) and (22 ps)(-1), respectively, while the backward ESIPT rates are (11 ps)(-1) and (48 ps)(-1) The ESIPT equilibrium constants are thus calculated to be 037 and 22 for II and III, respectively, giving a corresponding free energy change of 059 and -047 kcal/mol between normal and tautomer species For III, normal and tautomer emissions in solid are maximized at 435 and 580 nm, respectively, achieving a white light generation with Commission Internationale de l'Eclairage (CIE) (030, 027) An organic light-emitting diode based on III is also successfully fabricated with maximum brightness of 665 cd m(-2) at 20 V (885 mA cm(-2)) and the CIE coordinates of (026, 035) The results provide the proof of concept that the white light generation can be achieved in a single ESIPT systemread more
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Journal ArticleDOI
ESIPT on/off switching and crystallization-enhanced emission properties of new design phenol-pyrazole modified cyclotriphosphazenes
TL;DR: A nucleophilic substitution reaction of N3P3Cl2(2,2′-dioxybiphenyl)2 with 2-(1H-pyrazol-3-yl) phenol (2) was performed in order to synthesize molecules that may exhibit different photophysical properties on the cyclotriphosphazene scaffold as discussed by the authors.
Journal ArticleDOI
Spectroscopic and theoretical investigation into substituent- and aggregation-related dual fluorescence effects in the selected 2-amino-1,3,4-thiadiazoles
Iwona Budziak,Dariusz Karcz,Marcin Makowski,Beata Myśliwa-Kurdziel,Kamila Kasprzak,Alicja Matwijczuk,Edyta Chruściel,Anna Oniszczuk,Lidia Adwent,Arkadiusz Matwijczuk +9 more
TL;DR: In this article, the results of spectroscopic studies conducted on three compounds from the 1,3,4-thiadiazole group: 2-amino-5-phenyl-1, 3, 4-thiamidiazole (TB), 2-amide-5-(2-hydroxyphenyl)-1,3 4thiamide (TS), 2amide-6-(2.hydroxy-5)-sulfobenzoyl)-1.3, 4thamidine (TSF).
Journal ArticleDOI
Highly Selective Ratiometric Fluorescent Probes for Detection of Perborate Based on Excited‐State Intramolecular Proton Transfer (ESIPT) in Environmental Samples and Living Cells
Ajit Kumar Mahapatra,Sanchita Mondal,Saikat Kumar Manna,Kalipada Maiti,Rajkishor Maji,Syed Samim Ali,Sukhendu Mandal,Md. Raihan Uddin,Dilip K. Maiti +8 more
TL;DR: In this article, two excited-state intramolecular proton transfer (ESIPT)-based first ratiometric fluorescent probes were shown to be selective and sensitive for perborate (BO3-) among the 15 anions studied in HEPES buffer medium.
Journal ArticleDOI
Design, synthesis and photophysical investigation of triphenylamine-bithiophene dyes as RGB emitters for white light applications
Athira Krishna,Athira Krishna,E. Varathan,E. Varathan,Padincharapad Sreedevi,V. Subramanian,V. Subramanian,Venugopal Karunakaran,Venugopal Karunakaran,Ramavarma Luxmi Varma,Ramavarma Luxmi Varma +10 more
TL;DR: In this paper, a set of three triphenylamine-bithiophene based donor-acceptor (D-A) molecules viz. TPT, TPT-Ben and TPTAc were designed, synthesized and studied for their photophysical properties.
Journal ArticleDOI
White light generation using Förster resonance energy transfer between 3-hydroxyisoquinoline and Nile Red.
TL;DR: The films showed excellent photostability with 405 nm diode illumination, along with mechanical flexibility, suggesting good potential utility as a down converting element for lighting applications, and the extent of FRET could be regulated and the overall film emission color could be manipulated to enable overall "white" emission.
References
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Journal ArticleDOI
Density‐functional thermochemistry. III. The role of exact exchange
TL;DR: In this article, a semi-empirical exchange correlation functional with local spin density, gradient, and exact exchange terms was proposed. But this functional performed significantly better than previous functionals with gradient corrections only, and fits experimental atomization energies with an impressively small average absolute deviation of 2.4 kcal/mol.
Journal ArticleDOI
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density
TL;DR: Numerical calculations on a number of atoms, positive ions, and molecules, of both open- and closed-shell type, show that density-functional formulas for the correlation energy and correlation potential give correlation energies within a few percent.
Journal ArticleDOI
A new integral equation formalism for the polarizable continuum model: Theoretical background and applications to isotropic and anisotropic dielectrics
TL;DR: In this paper, a new integral equation formulation of the polarizable continuum model (PCM) is presented, which allows one to treat in a single approach dielectrics of different nature: standard isotropic liquids, intrinsically anisotropic medialike liquid crystals and solid matrices, or ionic solutions.
Journal ArticleDOI
Proton-Coupled Electron Transfer
David R. Weinberg,Christopher J. Gagliardi,Jonathan F. Hull,Christine Fecenko Murphy,Caleb A. Kent,Brittany C. Westlake,Amit Paul,Daniel H. Ess,Dewey G. McCafferty,Thomas J. Meyer +9 more
TL;DR: Proton-coupled electron transfer is an important mechanism for charge transfer in a wide variety of systems including biology- and materials-oriented venues and several are reviewed.
Journal ArticleDOI
Accuracy of AH n equilibrium geometries by single determinant molecular orbital theory
P.C. Hariharan,John A. Pople +1 more
TL;DR: In this paper, a simple level of ab initio molecular orbital theory with a split-valence shell basis with d-type polarization functions was used to predict equilibrium geometries for the ground and some low-lying excited states of AHn molecules and cations where A is carbon, nitrogen, oxygen or fluorine.
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