Journal ArticleDOI
Formal [1,3] rearrangement of 2-furylmethyl and 2-thienylmethyl vinyl ethers
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TLDR
For example, 2-furyl and 2-thicnylmelhyl vinyl ethers undergo formal [1,3] rearrangement in LPDE medium as discussed by the authors.About:
This article is published in Tetrahedron Letters.The article was published on 1995-12-25. It has received 11 citations till now.read more
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Formal (1,3) Rearrangement of 2-Furylmethyl and 2-Thienylmethyl Vinyl Ethers.
TL;DR: For example, 2-furyl and 2-thicnylmelhyl vinyl ethers undergo formal [1,3] rearrangement in LPDE medium as discussed by the authors.
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Book
Handbook of heterocyclic chemistry
TL;DR: The Handbook of Heterocyclic Chemistry as discussed by the authors has been updated with over 50% new content, including a new expanded author team, who have carefully distilled essential information on the reactivity, structure and synthesis of heterocycles.
Journal ArticleDOI
[1,3]-Sigmatropic rearrangement of allyl vinyl ethers at ambient temperature in 3.0 M lithium, perchlorate-diethyl ether
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Synthesis of glycosides of fucose under neutral conditions in solutions of LiClO4 in organic solvents
Gerd Böhm,Herbert Waldmann +1 more
TL;DR: In this paper, the glycosyl donors 2,3,4-tri-O-benzyl fucosyl fluoride and trichloroacetimidate are activated under neutral conditions in 1M solutions of LiClO 4 in CH 2 Cl 2 or ether to react with mono- and disaccharides to give fucoseyl glycosides in high yields and with high stereoselectivity.
Journal ArticleDOI
Direct substitution of secondary allylic alcohols with O-silylated ketene acetals in 3.0 M lithium perchlorate-diethyl ether - An alternative to the [1,3] sigmatropic rearrangement of allyl vinyl ethers
TL;DR: Allylic alcohols of type 1 undergo unprecedented substitution with O-silylated ketene acetals in 3.0 M lithium perchlorate-diethyl ether as discussed by the authors.