Journal ArticleDOI
Frontal polymerizations carried out in deep-eutectic mixtures providing both the monomers and the polymerization medium
Josué D. Mota-Morales,Josué D. Mota-Morales,María C. Gutiérrez,Isaac C. Sanchez,Gabriel Luna-Bárcenas,Francisco del Monte +5 more
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TLDR
Deep Eutectic Solvents based upon mixtures of Acrylic Acid or Methacrylic Acid and Choline Chloride demonstrated superior performance than regular organic solvents and even ionic liquids for frontal polymerizations (FPs).About:
This article is published in Chemical Communications.The article was published on 2011-04-19. It has received 113 citations till now. The article focuses on the topics: Methacrylic acid & Choline chloride.read more
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Deep Eutectic Solvents (DESs) and Their Applications
Journal ArticleDOI
Deep eutectic solvents: syntheses, properties and applications
TL;DR: All works discussed in this review aim at demonstrating that Deep Eutectic Solvents not only allow the design of eco-efficient processes but also open a straightforward access to new chemicals and materials.
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Three dimensional macroporous architectures and aerogels built of carbon nanotubes and/or graphene: synthesis and applications
TL;DR: This review aims to describe the different synthetic processes used for preparation of these three-dimensional architectures and/or aerogels containing either any or both allotropes, and the different fields of application in which the particular structure of these materials provided a significant enhancement in the efficacy as compared to their two-dimensional analogues or even opened the path to novel applications.
Journal ArticleDOI
Deep Eutectic Solvents: A Review of Fundamentals and Applications.
Benworth Hansen,Stephanie Spittle,Brian Chen,Derrick Poe,Yong Zhang,Jeffrey M. Klein,Alexandre Horton,Laxmi Adhikari,Tamar Zelovich,Brian W. Doherty,Burcu Gurkan,Edward J. Maginn,Arthur J. Ragauskas,Mark Dadmun,Thomas A. Zawodzinski,Gary A. Baker,Mark E. Tuckerman,Robert F. Savinell,Joshua Sangoro +18 more
TL;DR: A detailed review of the current literature reveals the lack of predictive understanding of the microscopic mechanisms that govern the structure-property relationships in deep eutectic solvents, and highlights recent research efforts to elucidate the next steps needed to develop a fundamental framework needed for a deeper understanding.
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Deep-eutectic solvents playing multiple roles in the synthesis of polymers and related materials
Daniel Carriazo,María Concepción Serrano,María C. Gutiérrez,Maria L. Ferrer,Francisco del Monte +4 more
TL;DR: The aim of this review is to provide an exposition of some of the most recent applications of deep-eutectic solvents (DESs) in the synthesis of polymers and related materials to encourage scientists to explore the promising perspectives offered by DESs.
References
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Applications of ionic liquids in the chemical industry
TL;DR: There have been parallel and collaborative exchanges between academic research and industrial developments since the materials were first reported in 1914, it is demonstrated.
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Novel solvent properties of choline chloride/urea mixtures
TL;DR: Eutectic mixtures of urea and a range of quaternary ammonium salts are liquid at ambient temperatures and have interesting solvent properties.
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Deep Eutectic Solvents Formed between Choline Chloride and Carboxylic Acids: Versatile Alternatives to Ionic Liquids
TL;DR: It is shown that the conductivity and viscosity of these liquids is controlled by ion mobility and the availability of voids of suitable dimensions, and this is consistent with the fluidity of other ionic liquids and molten salts.
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Advanced applications of ionic liquids in polymer science
Jianmei Lu,Feng Yan,John Texter +2 more
TL;DR: Ionic liquids (ILs) are continuing as important media in which to effect various kinds of polymerizations, and it is particularly noteworthy that ionic polymerization are being developed in IL solvents and that atom transfer radical polymerization (ATRP) catalysts are being attached to ILs to make them more easily recoverable in living polymerizations as mentioned in this paper.
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Application of hole theory to define ionic liquids by their transport properties.
TL;DR: The conductivity, viscosity, density, and surface tension of a number of glycolic mixtures with choline chloride are measured and it is proposed that the composition at which the measured conductivity matches the theoretical value is the point at which hole mobility becomes the dominant mechanism for charge mobility.