Journal ArticleDOI
Gold-catalyzed carbon-heteroatom bond-forming reactions.
TLDR
Application to Total Synthesis 1699 6.1.Abstract:
A.L.-P. thanks CSIC for a contract under the JAE-doctor
program. Financial support by PLE2009 project from MCIINN
and Consolider-Ingenio 2010 (proyecto MULTICAT) are also
acknowledged.read more
Citations
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Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles.
Lichen Liu,Avelino Corma +1 more
TL;DR: This Review will compare the results obtained from different systems and try to give a picture on how different types of metal species work in different reactions and give perspectives on the future directions toward better understanding of the catalytic behavior of different metal entities in a unifying manner.
Journal ArticleDOI
Gold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity
Ruth Dorel,Antonio M. Echavarren +1 more
TL;DR: Gold(I) complexes selectively activate π-bonds of alkenes in complex molecular settings, which has been attributed to relativistic effects as discussed by the authors, and are the most effective catalysts for the electrophilic activation of alkynes under homogeneous conditions.
Journal ArticleDOI
Gold catalysis in total synthesis—an update
TL;DR: In this critical review, the strongly increasing amount of new applications of gold catalysis in total synthesis is summarised and, for the new developed methods, the mode of activation of the substrate by the gold catalyst is discussed.
Journal ArticleDOI
Transition Metal-Mediated Synthesis of Monocyclic Aromatic Heterocycles
TL;DR: The present review is a transition metal-catalyzed synthesis of aromatic monocyclic heterocycles, aiming at achieving greater levels of molecular complexity and better functional group compatibilities in a convergent and atom economical fashions from readily accessible starting materials and under mild reaction conditions.
References
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Journal ArticleDOI
Engineering Metal Organic Frameworks for Heterogeneous Catalysis
TL;DR: In conclusion, MOFs as Host Matrices or Nanometric Reaction Cavities should not be considered as a source of concern in the determination of MOFs’ properties in relation to other materials.
Journal ArticleDOI
Gold-Catalyzed Organic Reactions
TL;DR: Important vinylgold intermediates, the transmetalation from gold to other transition metals, the development of new ligands for gold catalysis, and significant contributions from computational chemistry are other crucial points for the field highlighted here.
Journal ArticleDOI
Catalytic Carbophilic Activation: Catalysis by Platinum and Gold π Acids
Alois Fürstner,Paul W. Davies +1 more
TL;DR: The ability of platinum and gold catalysts to effect powerful atom-economic transformations has led to a marked increase in their utilization and the application of platinum- and gold-catalyzed transformations in natural product synthesis is discussed.
Book
Principles and applications of organotransition metal chemistry
TL;DR: A perspective survey of organotransition metal complexes according to ligand substitution processes can be found in this paper, with a focus on transition metal complexes with metal carbon-bonded ligands.
Journal ArticleDOI
Ligand effects in homogeneous Au catalysis.
TL;DR: The ways in which selectivity can be controlled in homogeneous Au catalysis are enumerated, in the hope that lessons to guide catalyst selection and the design of new catalysts may be distilled from a thorough evaluation of ligand, counterion, and oxidation state effects as they influence chemo-, regio-, and stereoselectivity in homogeneity AuCatalysis.