Journal ArticleDOI
Growth mechanism in the electropolymerization of aniline and p-aminodiphenylamine
About:
This article is published in Journal of Electroanalytical Chemistry.The article was published on 1986-12-24. It has received 83 citations till now. The article focuses on the topics: Aniline & Cyclic voltammetry.read more
Citations
More filters
Journal ArticleDOI
Polyaniline: A historical survey
TL;DR: A survey of the literature available on conducting organic polyaniline can be found in this paper, where the authors provide a survey of some of the most recent work on polyanILine.
Journal ArticleDOI
Cyclic potential sweep electropolymerization of aniline: The role of anions in the polymerization mechanism
TL;DR: In this paper, the cyclic potential sweep (CPS) method was applied to aniline electropolymerization in several strong acids (H 2 SO 4, HNO 3, HCl, HBF 4, HClO 4 and CF 3 COOH).
Journal ArticleDOI
Properties of electronically conductive polyaniline: a comparison between well-known literature data and some recent experimental findings
TL;DR: In this article, the synthesis and properties of polyaniline are discussed. But the most important result in this paper is a totally new reaction mechanism for the synthesis of polyanoiline, being the most detailed and comprehensive mechanism published to date.
Journal ArticleDOI
Formation of conducting polyaniline coatings on iron surfaces by electropolymerization of aniline in aqueous solutions
TL;DR: In this paper, aniline polyaniline was applied to an iron disc electrode in aqueous solutions by using various inorganic and organic acids under potentiodynamic, potentiostatic and galvanostatic conditions.
Journal ArticleDOI
Kinetic study of the chemical polymerization of aniline in aqueous solutions
K. Tzou,Richard V. Gregory +1 more
TL;DR: In this article, a semi-empirical kinetic equation, − d [ AN ] dt = k 1 [ AN ][ APS ] + k 2 ′[ AN ][ P ], where [P] = equivalent concentration of polymer, is proposed for this autoaccelerated reaction.
References
More filters
Journal ArticleDOI
Resistance of Polyaniline Films as a Function of Electrochemical Potential and the Fabrication of Polyaniline-Based Microelectronic Devices.
TL;DR: In this article, anodic growth of polyaniline films on a Au microelectrode array has been carried out to add to the characterization of polyanoiline and to fabricate polyanoin-based microelectronic devices, diodes and transistors, that function when the polyanoine-functionalized microelectron array is immersed in an electrolyte solution.
Journal ArticleDOI
Spectroelectrochemical study of polypyrrole films
E.M. Genies,G. Bidan,A.F. Diaz +2 more
TL;DR: The chronoabsorptometric results show that polypyrrole film grows linearly with time t and not t 1/2 as mentioned in this paper, which is consistent with the slow step in the growth process being a radical coupling step and not the diffusion of pyrrole to the electrode surface.
Journal ArticleDOI
Comparative theoretical study of the doping of conjugated polymers: Polarons in polyacetylene and polyparaphenylene
TL;DR: In this article, the physicochemical properties of all-trans polyacetylene and polyparaphenylene have been investigated in the framework of the adiabatic H\"uckel Hamiltonian with $\ensuremath{sigma}$-bond compressibility.
Journal ArticleDOI
Electrochemical studies of some conducting polythiophene films
TL;DR: In this paper, a property-structure correlation between monomers and their corresponding polymers is obtained by systematic variation of the chemical structure of the monomers, with conductivity of the order of 1 ohm/sup-1/ cm/sup -1/
Journal ArticleDOI
Electron-spin-resonance studies of pyrrole polymers: Evidence for bipolarons
TL;DR: In this paper, it was deduced that the ESR signal seen in the as-prepared material does not arise from the current-carrying species, but rather from accidental neutral ''ensuremath{\pi}$-radical defects''.
Related Papers (5)
Electrochemistry of Conductive Polymers II . Electrochemical Studies on Growth Properties of Polyaniline
David E. Stilwell,Su-Moon Park +1 more
Redox mechanism and electrochemical behaviour or polyaniline deposits
E.M. Genies,C. Tsintavis +1 more