Journal ArticleDOI
Heterogeneous catalysts for the selective aerobic oxidation of 5-hydroxymethylfurfural to added value products in water
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In this paper, the state of the art of the aerobic selective oxidation of 5-hydroxymetylfurfural (5-HMF) with heterogeneous catalysts in water is presented.About:
This article is published in Inorganica Chimica Acta.The article was published on 2018-01-30. It has received 50 citations till now. The article focuses on the topics: Catalysis.read more
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Supported gold- and silver-based catalysts for the selective aerobic oxidation of 5-(hydroxymethyl)furfural to 2,5-furandicarboxylic acid and 5-hydroxymethyl-2-furancarboxylic acid
TL;DR: In this article, the sustainable synthesis of two important intermediates relevant for the production of bio-based polymers, 2,5-furandicarboxylic acid (FDCA) and 5-hydroxymethyl-2-furancarboxyl acid (HFCA), via oxidation of 5-(hydroxyl)furfural (HMF) was investigated using supported gold and silver-based catalysts in water with air as the oxidant.
Journal ArticleDOI
Selective Aerobic Oxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran or 2-Formyl-5-furancarboxylic Acid in Water by using MgO⋅CeO2 Mixed Oxides as Catalysts.
María Ventura,Francesco Lobefaro,Elvira De Giglio,Monica Distaso,Francesco Nocito,Angela Dibenedetto +5 more
TL;DR: Mixed oxides based on MgO⋅CeO2 were used as efficient catalysts in the aerobic oxidation of 5-hydroxymethylfurfural to afford, with very high selectivity, either 2,5-diformylfuran (DFF) or 2-formyl-5-furancarboxylic acid (FFCA), depending on the reaction conditions.
Journal ArticleDOI
Oxidation of lignocellulosic platform molecules to value-added chemicals using heterogeneous catalytic technologies
Pedro L. Arias,Juan Antonio Cecilia,Inaki Gandarias,Jose Iglesias,Manuel López Granados,Rafael Mariscal,Gabriel Morales,Ramón Moreno-Tost,Pedro Maireles-Torres +8 more
TL;DR: In this article, an exhaustive overview about the heterogeneous catalytic technologies proposed for the oxidation of four key platform molecules (glucose, 5-hydroxymethylfurfural, furfural and levulinic acid) into important chemicals is presented.
Journal ArticleDOI
Tunable mixed oxides based on CeO2 for the selective aerobic oxidation of 5-(hydroxymethyl)furfural to FDCA in water
María Ventura,Francesco Nocito,Elvira De Giglio,Stefania Cometa,Angela Altomare,Angela Dibenedetto +5 more
TL;DR: In this paper, the use of Earth crust abundant new mixed oxides based on CeO2 for selective oxidation of 5-HMF to 2,5-furandicarboxylic acid (99%) in water, using oxygen as the oxidant.
Journal ArticleDOI
Stabilities, Regeneration Pathways, and Electrocatalytic Properties of Nitroxyl Radicals for the Electrochemical Oxidation of 5-Hydroxymethylfurfural
TL;DR: In this paper, the use of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and 4-acetamido-TemPO (ACT) for electrochemical HMF oxidation to FDCA was investigated.
References
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ReportDOI
Biomass as Feedstock for A Bioenergy and Bioproducts Industry: The Technical Feasibility of a Billion-Ton Annual Supply
Robert D. Perlack,Lynn L. Wright,Anthony F Turhollow Jr,Robin L. Graham,Bryce J. Stokes,Donald C Erbach +5 more
TL;DR: The U.S. Department of Energy and the United States Department of Agriculture have both strongly committed to expanding the role of biomass as an energy source as mentioned in this paper, and they support biomass fuels and products as a way to reduce the need for oil and gas imports; to support the growth of agriculture, forestry, and rural economies; and to foster major new domestic industries making a variety of fuels, chemicals, and other products.
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Conversion of biomass to selected chemical products
TL;DR: This critical review provides a survey illustrated by recent references of different strategies to achieve a sustainable conversion of biomass to bioproducts to examine critically the green character of conversion processes.
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Conversion of Biomass into Chemicals over Metal Catalysts
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Biomass into chemicals: Conversion of sugars to furan derivatives by catalytic processes
Xinli Tong,Yang Ma,Yongdan Li +2 more
TL;DR: Werpy et al. as mentioned in this paper reviewed the catalytic routes for the synthesis of 5-HMF, 2-5-FDCA, 2,5-DMF and other furanic derivatives from sugar.
Journal ArticleDOI
Catalytic Conversion of Cellulose into Sugar Alcohols
Atsushi Fukuoka,Paresh L. Dhepe +1 more
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