Journal ArticleDOI
Homogeneous catalytic hydrogenation of aldehydes and aldoses in organic solvents and water
Snježana Kolarić,Vitomir Šunjić +1 more
TLDR
In this paper, water-soluble homogeneous catalysts used for hydrogenation of aldehydes and aldoses are reviewed. Butler et al. focus on the mechanistic aspects of their activity and modes of their deactivation.Abstract:
Homogeneous catalysts used in hydrogenation of aldehydes and aldoses, mechanistic aspects of their activity, and modes of their deactivation are reviewed. Particular attention is paid to water soluble homogenous catalysts used for hydrogenation of sugars.read more
Citations
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Journal ArticleDOI
Deactivation in Homogeneous Transition Metal Catalysis: Causes, Avoidance, and Cure
Journal ArticleDOI
Bulk and fine chemicals via aqueous biphasic catalysis
TL;DR: Aqueous biphasic catalysis becomes more and more attractive for both bulk and fine chemical manufacture as discussed by the authors, and the use of homogeneous aqueous catalysis has been widely studied.
Journal ArticleDOI
Hydrogenation of fast pyrolyis oil and model compounds in a two-phase aqueous organic system using homogeneous ruthenium catalysts
TL;DR: The use of homogeneous ruthenium catalysts to hydrogenate the water-soluble fraction of pyrolysis oil is reported in this article, where the authors showed that the reaction was first order in substrate and zero order in hydrogen.
Journal ArticleDOI
Thermoregulated phase-transfer catalysis via PEG-armed Ru(II)-bearing microgel core star polymers : Efficient and reusable Ru(II) catalysts for aqueous transfer hydrogenation of ketones
TL;DR: In this article, the authors used a microgel-core star polymers with amphiphilic, thermosensitive poly(ethylene glycol) (PEG) arms [Ru(II)-PEG star], which were directly prepared by the ruthenium-catalyzed living radical polymerization in conjunction with a phosphine ligandcarrying styrene derivative.
Journal Article
Thermoregulated phase-transfer catalysis via PEG-armed Ru(II)-bearing microgel core star polymers: Efficient and reusable Ru(II) catalysts for aqueous transfer hydrogenation of ketones Part A Polymer chemistry
TL;DR: In this article, the authors used a microgel-core star polymers with amphiphilic, thermosensitive poly(ethylene glycol) (PEG) arms [Ru(II)-PEG star], which were directly prepared by the ruthenium-catalyzed living radical polymerization in conjunction with a phosphine ligand carrying styrene derivative.
References
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Journal ArticleDOI
The preparation and properties of tris(triphenylphosphine)halogenorhodium(I) and some reactions thereof including catalytic homogeneous hydrogenation of olefins and acetylenes and their derivatives
TL;DR: In this paper, the tris(triphenylphosphine) complexes are exceedingly active catalysts for the rapid and homogeneous hydrogenation, at ca. 1 atmosphere of hydrogen pressure and room temperature, of unsaturated compounds containing isolated olefinic and acetylenic linkages.
Book
Phase transfer catalysis
TL;DR: Ion Pairs and ion pair extraction as mentioned in this paper, the nature of phase transfer catalysis ion pairs in organic media Extraction of Ion Pairs from Aqueous Solution Crown Ethers, Cryptates, and Other Chelating Agents as Extractants Solid-Liquid Anion Exchange Mechanism of Phase Transfer Catalysis Mechanistic Investigations Empirical Catalyst Evaluations Unusual and Polymer Supported Catalysts Practical Applications of PTC Applications General Experimental Procedures Formation of Halides Preparation of Nitriles Ester Formation Miscellaneous Displacements Thiols and Sulfides Prepar
Journal ArticleDOI
Organic synthesis by means of noble metal compounds. XXXV. Novel decarbonylation reactions of aldehydes and acyl halides using rhodium complexes
Kiyotaka Ohno,Jiro Tsuji +1 more
Journal ArticleDOI
Dichlorotris(triphenylphosphine)ruthenium-catalyzed hydrogen transfer from alcohols to saturated and .alpha.,.beta.-unsaturated ketones
Yoel Sasson,Jochanan Blum +1 more
Book
Starch conversion technology
G.M.A. Van Beynum,J.A. Roels +1 more
TL;DR: An overview of processes by which starch is converted to a form which makes it more suitable for other applications is given in this paper with contributions by 17 international experts, including organic acids, alcohol, bipolymers, enzymes, amino acids, antibiotics and hormones.
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