Journal ArticleDOI
Homoleptic copper(II) and copper(I) complexes of 5,6-dihydro-5,6-epoxy-1,10-phenanthroline. Six-coordinate copper(I) in solution
Nirmal K. Shee,Debashree Das,F.A. Oluwafunmilayo Adekunle,F.A. Oluwafunmilayo Adekunle,Michael G. B. Drew,Dipankar Datta +5 more
TLDR
In this article, the X-ray crystal structure of the hemi acetonitrile solvate [CuL(3)](ClO(4))(2)center dot 6H(2)-O in methanol in 3:1 M ratio at room temperature was determined.About:
This article is published in Inorganica Chimica Acta.The article was published on 2011-01-30. It has received 13 citations till now.read more
Citations
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New redox-active layer create via epoxy-amine reaction - The base of genosensor for the detection of specific DNA and RNA sequences of avian influenza virus H5N1.
Kamila Malecka,Anna Stachyra,Anna Góra-Sochacka,Agnieszka Sirko,Włodzimierz Zagórski-Ostoja,Wim Dehaen,Hanna Radecka,Jerzy Radecki +7 more
TL;DR: A redox-active monolayer is developed and application for the construction of an electrochemical genosensor designed for the detection of specific DNA and RNA oligonucleotide sequences related to the avian influenza virus (AIV) type H5N1.
Journal ArticleDOI
Tuning the Copper(II)/Copper(I) Redox Potential for More Robust Copper-Catalyzed C–N Bond Forming Reactions
James D. Cope,Henry U. Valle,Ruby S. Hall,Kathleen M. Riley,Ekta Goel,Saborni Biswas,Michael P. Hendrich,David O. Wipf,Sean Stokes,Joseph P. Emerson +9 more
TL;DR: The role the 1,10-phenanthroline ligand plays on the electronic structure and redox properties of copper coordination complexes, and what benefit related ligands may provide to enhance copper-based coupling reactions is explored.
Journal ArticleDOI
Synthesis and DNA studies of a copper(II) complex of 5,6-dihydro-5,6-epoxy-1,10-phenanthroline
TL;DR: In this paper, a new copper(II) complex was synthesized and characterized by elemental analysis, IR and UV-vis spectroscopy, and single crystal X-ray diffraction.
Journal ArticleDOI
Silver(I) complexes with 1,10-phenanthroline-based ligands: The influence of epoxide function on the complex structure and biological activity
Sonja Ž. Đurić,Marija Mojicevic,Sandra Vojnovic,Hubert Wadepohl,Tina P. Andrejević,Nevena Lj. Stevanović,Jasmina Nikodinovic-Runic,Miloš I. Djuran,Biljana Đ. Glišić +8 more
TL;DR: Paramonov et al. as discussed by the authors reported the synthesis, characterization and biological evaluation of two silver(I) complexes with 1,10-phenanthroline-based ligands.
Journal ArticleDOI
A copper(II) complex with a Cu–S8 bond. Attenuated total reflectance, electron paramagnetic resonance, resonance Raman and atoms-in-molecule calculations
TL;DR: Satisfactory matching of the calculated and experimental IR spectra vindicates the theoretically derived structure of the cation in 2 and indicates that the S8 unit in 2 is bound to the metal.
References
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Journal ArticleDOI
EQNMR : a computer program for the calculation of stability constants from nuclear magnetic resonance chemical shift data
TL;DR: In this article, a computer program has been elaborated which uses the complexation-induced displacements of NMR chemical shifts to calculate the stability constants for the general reaction (i) which gives the generalised stability constant (ii).
Journal ArticleDOI
1,10-Phenanthrolines: versatile building blocks for luminescent molecules, materials and metal complexes
TL;DR: This tutorial review examines how the chemical versatility of pristine 1,10-phenanthroline, a weakly fluorescent molecule, has been exploited to design many UV-Vis-NIR luminescent organic derivatives and coordination compounds with transition-metal and rare-earth cations.
Journal ArticleDOI
Cu(CH3CN) 2 + , ein Mittel zum Studium homogener Reaktionen des einwertigen Kupfers in wässriger Lösung
P. Hemmerich,C. Sigwart +1 more
TL;DR: In this paper, the acidimetric investigation of CuI coordination reactions in homogeneous aqueous medium is feasible by application of the easily accessible, well crystallized stable complex Cu(CH3CN)4ClO4 in 0.1 to 1 molar CH3CN aq., the stability of particles present in the system CuI, CH 3CN, H2O being previously established polarographically.
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Metal-betaine interactions. Part 17: A study of intradimer Cu · · · Cu distance variation in copper(II) betaine complexes containing [Cu2 (carboxylato-O,O′)4L2]n+ species
Xiao-Ming Chen,Thomas C. W. Mak +1 more