Journal ArticleDOI
Hydrodechlorination kinetics and reaction mechanisms
A.H. Weiss,K.A. Krieger +1 more
TLDR
In this paper, the reactions of cis-and trans-dichloroethylenes with H2 over platinum-on-alumina catalysts have been characterized, and it is assumed that olefinic chlorides are adsorbed on the catalyst as stabilized tautomers.About:
This article is published in Journal of Catalysis.The article was published on 1966-10-01. It has received 36 citations till now. The article focuses on the topics: Reaction mechanism & Double bond.read more
Citations
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Journal ArticleDOI
Palladium-silver sol-gel catalysts for selective hydrodechlorination of 1,2-dichloroethane into ethylene. I. Synthesis and characterization
TL;DR: In this article, low-density xerogel Pd-Ag/SiO2 catalysts were prepared by a cogelation of tetraethoxysilane with organically substituted alkoxides capable of forming chelates with palladium and silver ions.
Journal ArticleDOI
Hydrodechlorination of aliphatic organochlorinated compounds over commercial hydrogenation catalysts
TL;DR: In this paper, eight commercial catalysts (Nickel-Raney, Ni on SiO2, Pd on alumina, Pt on both alumina and activated carbon, Rh on alumin, Ru and sulfided Ni-Mo on aluminina) were tested as catalysts for the hydrodechlorination of the six organochlorinated compounds that are released into the environment in the greatest amounts: dichloromethane, chloroform, carbon tetrachloride, 1,1,1-trichloroethane, trich
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Catalytic hydrodechlorination of chlorinated ethenes by nanoscale zero-valent iron
TL;DR: In this paper, the reduction of six chlorinated ethenes by nanoscale iron was investigated under five different conditions of initial dissolved hydrogen concentrations which varied from about 0.02 to 1.2 mM.
Journal ArticleDOI
Vapour-phase hydrodehalogenation of chlorobenzene over platinum/H-BEA zeolite
TL;DR: Platinum/H-BEA zeolite and Pt/Al 2 O 3 were studied as catalysts in the vapour-phase hydrodehalogenation of chlorobenzene as discussed by the authors.
Journal ArticleDOI
Characterisation and deactivation studies of sulfided red mud used as catalyst for the hydrodechlorination of tetrachloroethylene
TL;DR: In this paper, the deactivation of sulfided red mud as a catalyst for the hydrodechlorination of tetrachloroethylene at 100 bar and 350°C was studied.
References
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Book
Chemical Reaction Engineering
TL;DR: An overview of Chemical Reaction Engineering is presented, followed by an introduction to Reactor Design, and a discussion of the Dispersion Model.
Journal ArticleDOI
cis- and trans-Dichloroethylenes. The Infrared Spectra from 130-400 Cm.-1 and the Thermodynamic Properties1
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A bond energy scheme for aliphatic and benzenoid compounds
TL;DR: In this article, the authors developed a bond energy scheme based on the assumption that the energy of a CX bond depends on the hybridization state of the carbon atom.
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The C–C Bond Energy in Ethylbenzene
TL;DR: In this article, the energy of activation and the frequency factor were estimated experimentally at 63.2 kcal/mole and 1.0·1013 sec, respectively, and using this value in conjunction with the value reported previously for D(C-H)C6H5·CH3 and the relevant thermochemical data, they calculated the D (C−H)CH4 at 102.9 kcal./mole.