Journal ArticleDOI
Hydrogen adsorption on metal surfaces
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TLDR
In this paper, extensive calculations of the ground state properties of hydrogen chemisorbed on transition metal surfaces are performed using the effective medium theory, and the results for the chemical energy on all the 3D, 4D and 5D metals presented are in good agreement with experiment.About:
This article is published in Surface Science.The article was published on 1984-01-01. It has received 310 citations till now. The article focuses on the topics: Bond length & Surface diffusion.read more
Citations
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Electronic factors determining the reactivity of metal surfaces
Bjørk Hammer,Jens K. Nørskov +1 more
TL;DR: In this article, the authors present a consistent picture of some key physical properties determining the reactivity of metal and alloy surfaces, and suggest that trends in reactivities can be understood in terms of the hybridization energy between the bonding and anti-bonding adsorbate states and the metal d-bands (when present).
Journal ArticleDOI
The embedded-atom method: a review of theory and applications
TL;DR: The embedded-atom method (EAM) as mentioned in this paper is a semi-empirical method for performing calculations of defects in metals, and it has been shown to provide a very useful and robust means of calculating approximate structure and energetics.
Journal ArticleDOI
Interaction of hydrogen with solid surfaces
TL;DR: In this article, the authors focus on the chemosorptive and physisorptive behavior of hydrogen interacting with solid surfaces and discuss the effect of these interactions on the structure of the underlying solid surfaces.
Journal ArticleDOI
Surface infrared spectroscopy
TL;DR: The theoretical and experimental foundation of surface IR spectroscopy is described and selected examples are presented to illustrate the kind of information derived in several important areas of surface science such as chemistry, structure, dynamics and kinetics at surfaces as discussed by the authors.
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Hydrogen desorption from the monohydride phase on Si(100)
Kumar Sinniah,Michael G. Sherman,Lisa B. Lewis,W. Henry Weinberg,John T. Yates,Kenneth C. Janda +5 more
TL;DR: In this paper, it was shown that the rate limiting step of the reaction is the promotion of a hydrogen atom from a localized bonding site to a delocalized band state, which then reacts with a localized atom to produce molecular hydrogen which desorbs.
References
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Book
Chemistry and physics of solid surfaces
Ralf Vanselow,Russell Howe +1 more
TL;DR: This volume contains review articles which were written by the invited speak- ers of the Sixth International Summer Institute in Surface Science (ISISS), held at the University of Wisconsin-Milwaukee in August 1983.
Journal ArticleDOI
Adsorption of hydrogen on palladium single crystal surfaces
TL;DR: In this article, the adsorption of hydrogen on clean Pd(110) and Pd (111) surfaces as well as on a Pd-111 surface with regular step arrays was studied by means of LEED, thermal desorption spectroscopy and contact potential measurements.
Journal ArticleDOI
Chemisorption geometry of hydrogen on Ni(111): Order and disorder
TL;DR: In this paper, the location of a half monolayer of ordered hydrogen adatoms on Ni(111) has been analyzed by Low-Energy Electron Diffraction (LEED), Thermal Desorption Spectroscopy (TDS), and Work Function (Δφ) measurements.
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Bonding of H to Ni, Pd, and Pt Surfaces
TL;DR: In this paper, angle-resolved photoelectron spectroscopy was used to study the bonding of H to the (111) surfaces of Ni, Pd, and Pt.