Journal ArticleDOI
Hydrogenation of carbon monoxide by ruthenium complexes with iodide promoters: catalytic and mechanistic investigations
Reads0
Chats0
TLDR
In this paper, two ruthenium complexes, HRu3(CO)11− and Ru( CO)3I3−, are shown to be essential for optimum activity during catalysis.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1983-07-05. It has received 67 citations till now. The article focuses on the topics: Ruthenium & Catalysis.read more
Citations
More filters
Journal ArticleDOI
A Review of Recent Literature to Search for an Efficient Catalytic Process for the Conversion of Syngas to Ethanol
TL;DR: In this paper, the authors proposed an alternative to petroleum-derived fuels and chemicals using renewable energy sources such as biomass, which can also serve as a feedstock for the synthesis of a variety of industrial chemicals and polymers.
Journal ArticleDOI
Recent advances in the homogeneous hydrogenation of carbon dioxide
TL;DR: A survey of the field can be found in this article, where the authors show that while very active catalysts and co-catalysts have been discovered in this period for the production of formic acid and its derivatives, there has been only preliminary development of homogeneous catalysts for other oxygenates (e.g. methanol, CO) and C n -compounds (n > 1).
Journal ArticleDOI
Selective Catalytic Synthesis Using the Combination of Carbon Dioxide and Hydrogen: Catalytic Chess at the Interface of Energy and Chemistry
TL;DR: The present Review highlights the challenges and opportunities when using the combination CO2 /H2 as a C1 synthon in catalytic reactions and processes, covering the value chain from high volume basic chemicals to complex molecules, including biologically active substances.
Journal ArticleDOI
Progress in biofuel production from gasification
TL;DR: In this paper, a review of the progress in gasification techniques and key generation pathways for biofuel production, process design and integration and socio-environmental impacts of biofuel generation are discussed, with the goal of investigating gasification-to-biofuels credentials as a sustainable and eco-friendly technology.
Journal ArticleDOI
Homogeneous hydrogenation of carbon dioxide to methanol
TL;DR: In this paper, homogeneous catalytic hydrogenation of CO2 and its derivatives into methanol is highlighted in combination with mechanistic understanding on a molecular level, in order to understand the interaction of active catalytic species with CO2 or hydrogen.
References
More filters
Journal ArticleDOI
The catalytic synthesis of hydrocarbons from H2CO mixtures over the group VIII metals: I. The specific activities and product distributions of supported metals
TL;DR: In this paper, specific catalysts were determined in the synthesis of hydrocarbons from CO-H2 mixtures over all the Group VIII metals except Os, and the methanation reaction was fitted to a power rate law of the form r CH 4 = Ae −Em RT P H 2 X P CO Y over all groups VIII metals.
Journal ArticleDOI
Rational mechanism for homogeneous hydrogenation of carbon monoxide to alcohols, polyols, and esters
Journal ArticleDOI
Homogeneous carbon monoxide hydrogenation to methanol catalyzed by soluble ruthenium complexes
Journal ArticleDOI
Hydrogenation of carbon monoxide to methanol and ethylene glycol by homogeneous ruthenium catalysts
TL;DR: In contrast to previous reports of catalysis under extreme pressures, these studies were conducted at pressures of 340 atm and below as discussed by the authors and showed that carbon monoxide hydrogenation in these catalytic reactions (in several types of solvents) are nearly equal to those recently reported for a similar ruthenium system operated at much higher pressure.
Journal ArticleDOI
Ethylene glycol from synthesis gas via ruthenium melt catalysis
TL;DR: The Katalyse an geschmolzenen Tetrabutylphosphoniumsalzen, in denen RuO2 oder dessen Hydrat oder Ru(III)-acetylacetonat dispergiert sind, ergibt bei 100°C and 430 at Gesamtausb as mentioned in this paper.