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Journal ArticleDOI

Impedance parameters and the state-of-charge. II. Lead-acid battery

TLDR
In this article, it was shown that the internal impedance of a lead-acid battery is controlled by charge transfer and diffusion processes in the frequency range 15-100 Hz. But this was based on a uniform transmission line analog equivalent circuit for the battery electrodes.
Abstract
The determination of the state-of-charge of the lead-acid battery has been examined from the viewpoint of internal impedance. It is shown that the impedance is controlled by charge transfer and to a smaller extent by diffusion processes in the frequency range 15–100 Hz. The equivalent series/parallel capacitance as well as the a.c. phase-shift show a parabolic dependence upon the state-of-charge, with a maximum or minimum at 50% charge. These results are explained on the basis of a uniform transmission-line analog equivalent circuit for the battery electrodes.

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Citations
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Journal ArticleDOI

A review of impedance measurements for determination of the state-of-charge or state-of-health of secondary batteries

TL;DR: A detailed review of the applicability of impedance measurement as a test of state-of-charge or state of health of battery cells has been performed in both scientific journals and technical conferences.
Journal ArticleDOI

New dynamical models of lead-acid batteries

TL;DR: In this paper, the main results of studies that have been carried out, during a period of more than a decade, at University of Pisa in co-operation with other technical Italian institutions, about models of electrochemical batteries suitable for the use of the electrical engineer, in particular for the analysis of electrical systems with batteries.
Journal ArticleDOI

A review of state-of-charge indication of batteries by means of a.c. impedance measurements

TL;DR: In this article, a review consolidates the literature on the prediction of the state-of-charge (SoC) of batteries by means of a.c. impedance measurements.
Journal ArticleDOI

Dynamical Models of Lead-Acid Batteries: Implementation Issues

TL;DR: In this article, Ceraolo et al. explained how the lead-acid models described in a previous paper can be used in practice and provided detailed information on how to identify the several parameters of the proposed models, and defined a whole family of models, but did not discuss which model of the family is adequate for a given purpose.
Journal ArticleDOI

The impedance of electrical storage cells

TL;DR: In this paper, a brief review of the theory pertaining to the impedance of electrolytic cells is presented, and differences between the operational representations of cell impedances in the fields of electrochemistry and electrical engineering are noted.
References
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Journal ArticleDOI

The electrochemical behavior of the nickel – nickel oxide electrode: part i. kinetics of self-discharge

TL;DR: In this paper, the positive plate of a charged nickel-cadmium battery is formed by the NiO 2 oxide electrode (NiO 2 ), which forms a positive plate in the battery.
Journal ArticleDOI

Impedance parameters and the state-of charge. I. Nickel-cadmium battery

TL;DR: In this paper, the problem of non-destructive determination of the state of charge of nickel-cadmium batteries has been examined experimentally and theoretically from the viewpoint of internal impedance, and it is shown that the modulus of the impedance is mainly controlled by diffusion at all states of charge.
Journal ArticleDOI

Electrochemistry of the nickel oxide electrode: part iii. anodic polarization and self-discharge behavior

TL;DR: In this article, the rate-controlling process in self-discharge of the nickel oxide electrode is the anodic partial reaction of oxygen evolution, based on a comparison of the two processes.
Journal ArticleDOI

Orthogonal components of the impedance of batteries by a simple technique

TL;DR: In this article, the internal impedance of a power source with resistive and reactive components is intimately related to the effective area of the electrodes, kinetics of the electrode processes and transport properties of the ions in the system.
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