Journal ArticleDOI
In-situ generation of fluorinated polycarbonate copolymer solid electrolytes for high-voltage Li-metal batteries
TLDR
In this paper , a fluorine-containing polycarbonate-based electrolyte was designed to expand the electrochemical window up to above 5 V (vs. Li/Li+ ), which exhibited an ionic conductivity of 5.02 × 10 −5 S cm −1 at room temperature.About:
This article is published in Energy Storage Materials.The article was published on 2022-03-01. It has received 31 citations till now. The article focuses on the topics: Electrolyte & Polycarbonate.read more
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Journal ArticleDOI
Are Polymer‐Based Electrolytes Ready for High‐Voltage Lithium Battery Applications? An Overview of Degradation Mechanisms and Battery Performance
Maria Ángeles Cabañero Martínez,Nicola Boaretto,Andrew J. Naylor,Francisco Alcaide,Girish D. Salian,Flavia Palombardini,Elixabete Ayerbe,Mateu Borràs,Montse Casas-Cabanas +8 more
TL;DR: In this paper , the oxidative stability of polymer electrolytes is comprehensively discussed, along with the key sources of cell degradation, and an overview of the fundamental strategies adopted for enhancing their cyclability.
Journal ArticleDOI
8.5 µm‐Thick Flexible‐Rigid Hybrid Solid–Electrolyte/Lithium Integration for Air‐Stable and Interface‐Compatible All‐Solid‐State Lithium Metal Batteries
Kun Zhang,Feng Wu,Xinran Wang,Suting Weng,Xiaoyuan Yang,Huichun Zhao,Ruiqi Guo,Yuheng Sun,Wenbin Zhao,Tinglu Song,Xuefeng Wang,Yinglong Bai,Chuan Wu +12 more
TL;DR: In this article , an air-stable and interface-compatible solid electrolyte/lithium integration is proposed by in situ copolymerization of poly(ethylene glycol methacrylate)−Li 1.5Al0.5Ge1.5(PO4)3−lithIUM (PEGMA•LAGP‐Li).
Journal ArticleDOI
Recent progress in lithium-ion and lithium metal batteries
TL;DR: A review of the main progress in the development of lithium-ion batteries and LMBs can be found in this paper , where the main goal is to solve the problem of instability of layered nickel-rich lithium-rich NMC cathodes, as well as silicon anodes.
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Ion transport in composite polymer electrolytes
TL;DR: The polymer-based electrolytes are highly valued for solid-state batteries with high energy density and safety as discussed by the authors , owing to their high flexibility, remarkable processability, and favorable interfacial contacts with electrodes.
Journal ArticleDOI
Fluorinated Strategies Among All‐Solid‐State Lithium Metal Batteries from Microperspective
Fan Yang,Yujing Liu,Tiefeng Liu,Yao Wang,Jianwei Nai,Z. Lin,Hao Xu,Dan Duan,Ke Yue,Xinyong Tao +9 more
TL;DR: In this article , the progress of fluorinated strategies in all-solid-state lithium metal batteries (ASSLMBs) is summarized from the aspects of fluorinating SEs and fluorinated interfaces.
References
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Journal ArticleDOI
Challenges for Rechargeable Li Batteries
John B. Goodenough,Youngsik Kim +1 more
TL;DR: In this paper, the authors reviewed the challenges for further development of Li rechargeable batteries for electric vehicles and proposed a nonflammable electrolyte with either a larger window between its lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) or a constituent that can develop rapidly a solid/ electrolyte-interface (SEI) layer to prevent plating of Li on a carbon anode during a fast charge of the battery.
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Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.
TL;DR: The phytochemical properties of Lithium Hexafluoroarsenate and its Derivatives are as follows: 2.2.1.
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Reviving the lithium metal anode for high-energy batteries
TL;DR: The current understanding on Li anodes is summarized, the recent key progress in materials design and advanced characterization techniques are highlighted, and the opportunities and possible directions for future development ofLi anodes in applications are discussed.
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Nanocomposite polymer electrolytes for lithium batteries
TL;DR: In this article, the authors showed that nanometre-sized ceramic powders can be used as solid plasticizers for polyethylene oxide (PEO) electrolytes to prevent crystallization on annealing from amorphous state above 60°C.