Journal ArticleDOI
Infrared and Raman spectra of the M+F3- ion pairs and their mixed chlorine-fluorine counterparts in solid argon
Bruce S. Ault,Lester Andrews +1 more
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This article is published in Inorganic Chemistry.The article was published on 1977-08-01. It has received 67 citations till now. The article focuses on the topics: Raman spectroscopy & Argon.read more
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The Halogen Bond
Gabriella Cavallo,Pierangelo Metrangolo,Pierangelo Metrangolo,Roberto Milani,Tullio Pilati,Arri Priimagi,Giuseppe Resnati,Giancarlo Terraneo +7 more
TL;DR: The specific advantages brought up by a design based on the use of the halogen bond will be demonstrated in quite different fields spanning from material sciences to biomolecular recognition and drug design.
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A different story of pi-delocalization--the distortivity of pi-electrons and its chemical manifestations.
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The fluorine atom as a halogen bond donor, viz. a positive site
Pierangelo Metrangolo,Jane S. Murray,Tullio Pilati,Tullio Pilati,Peter Politzer,Giuseppe Resnati,Giuseppe Resnati,Giancarlo Terraneo +7 more
TL;DR: When bound to residues which can work as particularly strong electron withdrawing groups, fluorine can display a region of positive electrostatic potential (positive σ-hole) as discussed by the authors, which can thus function as a halogen bond donor and form complexes with lone-pair-containing neutral atoms and anions.
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"Frozen" Transition States: Pentavalent Carbon et al.
TL;DR: This work has generated a molecule that is an analog of the transition state for the associative nucleophilic displacement reaction, a pentavalent carbon species that has been observed by nuclear magnetic resonance spectroscopy.
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Recent Discoveries of Polyhalogen Anions – from Bromine to Fluorine
Heike Haller,Sebastian Riedel +1 more
TL;DR: In this article, the authors discuss the recent discoveries in polyhalide anion chemistry with the main focus on polybromide, -chloride, and -fluoride anions.
Related Papers (5)
Matrix reactions of alkali metal fluoride molecules with fluorine. Infrared and Raman spectra of the trifluoride ion in the M+F3- species
Bruce S. Ault,Lester Andrews +1 more