Journal ArticleDOI
Intermolecular aminotrifluoromethylation of alkenes by visible-light-driven photoredox catalysis.
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TLDR
The present photocatalytic protocol achieves highly efficient and regioselective difunctionalization of C═C bonds, leading to a variety of β-trifluoromethylamines.About:
This article is published in Organic Letters.The article was published on 2013-04-19. It has received 267 citations till now. The article focuses on the topics: Photoredox catalysis.read more
Citations
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Good Partnership between Sulfur and Fluorine: Sulfur-Based Fluorination and Fluoroalkylation Reagents for Organic Synthesis
Chuanfa Ni,Mingyou Hu,Jinbo Hu +2 more
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Carbon trifluoromethylation reactions of hydrocarbon derivatives and heteroarenes.
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Addition of CF3 across unsaturated moieties: a powerful functionalization tool
Estíbaliz Merino,Cristina Nevado +1 more
TL;DR: This review summarizes recent methodologies for the simultaneous formation of C–CF3 and C–C or C–heteroatom bonds by formal addition reactions to alkenes.
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Trifluoromethylation of Alkenes with Concomitant Introduction of Additional Functional Groups
Hiromichi Egami,Mikiko Sodeoka +1 more
TL;DR: This review focuses on recent advances in the difunctionalizing trifluoromethylation of alkenes with concomitant introduction of additional functional groups.
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Fine Design of Photoredox Systems for Catalytic Fluoromethylation of Carbon–Carbon Multiple Bonds
Takashi Koike,Munetaka Akita +1 more
TL;DR: This Account focuses on recent research on photoredox-catalyzed fluoromethylation of carbon-carbon multiple bonds in organofluorine compounds bearing C(sp(3))-CF3 bonds and choices of the photocatalyst and the fluorometrichylating reagent are explained.
References
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Journal ArticleDOI
Fluorine in Pharmaceuticals: Looking Beyond Intuition.
TL;DR: Experimental progress in exploration of the specific influence of carbon-fluorine single bonds on docking interactions is reviewed and complementary analysis based on comprehensive searches in the Cambridge Structural Database and the Protein Data Bank is added.
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Visible light photoredox catalysis: applications in organic synthesis
TL;DR: This tutorial review provides a historical overview of visible light photoredox catalysis in organic synthesis along with recent examples which underscore its vast potential to initiate organic transformations.
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Visible light photocatalysis as a greener approach to photochemical synthesis
TL;DR: Transition metal photocatalysis represents a promising strategy towards the development of practical, scalable industrial processes with great environmental benefits.
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Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes
TL;DR: The enantioselective intermolecular α-alkylation of aldehydes has been accomplished using an interwoven activation pathway that combines both the photoredox catalyst Ru(bpy)3Cl2 and an imidazolidinone organocatalyst.
Journal ArticleDOI
Visible-light photoredox catalysis.
Jun Xuan,Wen-Jing Xiao +1 more
TL;DR: Recent advances made in this fast developing area of research are discussed in the Minireview of visible-light-promoted photocatalytic reactions.