Journal ArticleDOI
Interpenetrated Three-Dimensional Networks of Hydrogen-Bonded Organic Species: A Systematic Analysis of the Cambridge Structural Database
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In this paper, the authors describe the comprehensive results of their investigation of interpenetration in organic hydrogen-bonded 3D arrays from the Cambridge Structural Database (CSDB).Abstract:
Interpenetration in extended three-dimensional (3D) arrays has been investigated by a systematic analysis of the crystallographic structural databases, using an ad hoc version of the program package TOPOS. In this paper we describe the comprehensive results of our investigation of interpenetration in organic hydrogen-bonded 3D arrays from the Cambridge Structural Database. The great interest in the self-assembly of organic molecules into hydrogen-bonded supramolecular arrays has prompted us to investigate these systems at a rather unusual level; that is, beyond the formation of synthons, we have examined the topologies of the resulting networks and looked for their entanglements. Within 3D architectures we have extracted a complete list including 122 different motifs showing the phenomenon of interpenetration (76 unseen by the original authors). These organic networks include species assembled by a single or by different building blocks; they are discussed and classified according to the previously introd...read more
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Journal ArticleDOI
Applied Topological Analysis of Crystal Structures with the Program Package ToposPro
Vladislav A. Blatov,Vladislav A. Blatov,A. P. Shevchenko,Davide M. Proserpio,Davide M. Proserpio +4 more
TL;DR: ToposPro as mentioned in this paper is a topological analysis of crystal structures realized in the current version of the program package ToposPro, which can be used to analyze various classes of chemical compounds including coordination polymers, molecular crystals, supramolecular ensembles, inorganic ionic compounds, intermetallics, fast-ion conductors, microporous materials.
Journal ArticleDOI
MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)
Christoph Janiak,Jana K. Vieth +1 more
TL;DR: In this paper, a review of metal-organic frameworks (MOFs) and porous coordination polymers (PCPs) with selected examples of their structures, concepts for linkers, syntheses, post-synthesis modifications, metal nanoparticle formations in MOFs, porosity and zeolitic behavior for applications in gas storage for hydrogen, carbon dioxide, methane and applications in conductivity, luminescence and catalysis.
Journal ArticleDOI
Recent advances in crystal engineering
TL;DR: The 10th edition of CrystEngComm as mentioned in this paper highlighted the state-of-the-art of crystal engineering and new trends and developing areas in crystal engineering, such as intermolecular interactions, metal-organic frameworks or coordination polymers; polymorphism and solvates.
Journal ArticleDOI
Underlying nets in three-periodic coordination polymers: topology, taxonomy and prediction from a computer-aided analysis of the Cambridge Structural Database
TL;DR: A recently developed approach to formalize the analysis of extended architectures by successive simplifications of a crystal structure perceived as a periodic net is discussed and the up-to-date methods for prediction of the topology of underlying nets are discussed.
Journal ArticleDOI
Interpenetration control in metal–organic frameworks for functional applications
TL;DR: An overview of interpenetration involved in coordination polymers with different dimensionalities and property changes (including gas uptake capabilities and catalysis) is provided in this paper, where several approaches for control of interbenetration in MOFs have also been introduced and summarized.
References
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