Journal ArticleDOI
KINETIC ANALYSIS OF THERMOGRAVIMETRIC DATA XXVIII Thermal decomposition of some metal and ammonium salts of hexabromoplatinic acid
TLDR
In this paper, the thermal decomposition of hexabromoplatinie acid was studied by derivatograph and differential scanning calorimetry, and the natures of pyrolysis processes were discussed and compared with those obtained for the analogous ehlorocomplexes.Abstract:
The potassium, ammonium and thirteen amine salts of hexabromoplatinie acid were obtained and characterized by chemical analysis. The thermal decompositions of these complex salts were studied by derivatograph and differential scanning calorimetry. The natures of the pyrolysis processes are discussed and compared with those obtained for the analogous ehlorocomplexes. From the TG curves, kinetic parameters were derived for different stages of the thermal decomposition.read more
Citations
More filters
Journal ArticleDOI
Pyrolysis characteristics and kinetics of microalgae via thermogravimetric analysis (TGA): A state-of-the-art review.
Quang-Vu Bach,Wei Hsin Chen +1 more
TL;DR: A state-of-the art review on recent research activities in pyrolysis characteristics and kinetics of various microalgae, includingThermogravimetric analysis, and common kinetic models predicting the thermal degradation ofmicroalgae are examined.
Journal ArticleDOI
The kinetic analysis of the pyrolysis of agricultural residue under non-isothermal conditions.
TL;DR: The study concerns the pyrolysis kinetics of agricultural wastes, corn straw and rice husk, and Iso-conversional Starink approach and Avrami theory were used to evaluate the kinetic parameters, including apparent activation energy and reaction order.
Journal ArticleDOI
Pyrolysis treatment of oil sludge and model-free kinetics analysis
TL;DR: Various approaches including thermogravimetric analysis, CNHS/O elemental analysis, electrically heated fixed bed quartz reactor coupled with Vario Plus emission monitoring system, and oil-gas evaluation workstation equipped with a flame ionization detector (FID) were used to investigate pyrolysis of tank bottom oil sludge.
Book ChapterDOI
Structural Characteristics and Thermal Properties of Native Cellulose
TL;DR: In this paper, a review and a review of cellulose research is presented. But the main focus of the review is on cellulose derivatives, which are used for coatings, laminates, optical films and sorption media, as well as for property-determining additives in building materials, composites and nanocomposites, pharmaceuticals, foodstuffs and cosmetics.
Journal ArticleDOI
Ozawa’s kinetic method for analyzing thermoanalytical curves
TL;DR: In this article, the theoretical basis and historical perspective of Ozawa's nonisothermal kinetic method for analyzing thermoanalytical curves are investigated by reviewing the history of thermal analysis and its application to the kinetic analysis of the solid-state processes.
References
More filters
Journal ArticleDOI
Kinetic analysis of thermogravimetric data
TL;DR: In this article, computer programs are given in Fortran language for three integral methods of deriving kinetic parameters from TG curves, one is a computerized variant of Doyle's curve-fitting method and performs the calculation of the exponential integralp(x) by means of author's empirical formula.
Journal ArticleDOI
The Stereochemistry of Complex Inorganic Compounds. X. The Stereoisomers of Dichlorobis-(ethylenediamine)-platinum (IV) Chloride1
Journal ArticleDOI
The kinetic compensation effect
TL;DR: The lack of physical significance of n, E, and Z for thermal decompositions is recognized by both authors as mentioned in this paper, and the disagreement lies in the value of using these parameters when the complete rate equation is not known.
Journal ArticleDOI
Isoparametric kinetic relations for chemical transformations in condensed substances (Analytical survey). II. Reactions involving the participation of solid substances
A. I. Lesnikovich,S. V. Levchik +1 more
TL;DR: In this article, various manifestations of the kinetic compensation effect are considered in reactions involving the participation of solid substances under isothermal and nonisothermal conditions, as well as manifestations of other isoparametric correlations.
Related Papers (5)
Kinetic analysis of non-isothermal decomposition of Fe2+, Co2+, Ni2+ and Cu2+ succinate complexes in a nitrogen atmosphere
Thermal decomposition of calcium copper acetate hexahydrate by simultaneous measurement of controlled-rate thermogravimetry and mass spectrometry (CRTG-MS)
Tadashi Arii,Yoshio Masuda +1 more