Journal ArticleDOI
Kinetic study of the photo-induced copolymerization of N-substituted maleimides with electron donor monomers
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TLDR
In this paper, the photo-induced copolymerization of electron donor/electron acceptor monomers has been studied by real-time infrared spectroscopy, and the reaction was found to proceed rapidly upon u.v. exposure in the absence of oxygen.About:
This article is published in Polymer.The article was published on 1999-04-01. It has received 84 citations till now. The article focuses on the topics: Maleimide & Copolymer.read more
Citations
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Photopolymerization kinetics of multifunctional monomers
TL;DR: In this paper, the main emphasis is given to the propagation and termination rate coefficients and to the determination of the mechanism of the termination process, and a comparison with the kinetics of linear polymerizations has been made.
Journal ArticleDOI
Strategies to Reduce Oxygen Inhibition in Photoinduced Polymerization
Samuel Clark Ligon,Branislav Husár,Branislav Husár,Harald Wutzel,Richard Holman,Robert Liska +5 more
TL;DR: Type II triplet quenching of aryl thiols was found to be dependent on the sensitizer, viscosity, and hydrogen-donating capability of the monomer and on the presence of oxygen.
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Biobased Amines: From Synthesis to Polymers; Present and Future.
Vincent Froidevaux,Claire Negrell,Sylvain Caillol,Jean-Pierre Pascault,Jean-Pierre Pascault,Bernard Boutevin +5 more
TL;DR: Amines are key intermediates in the chemical industry due to their nucleophilic characteristic which confers a high reactivity to them, and they are key monomers for the synthesis of polyamides, polyureas, polyepoxydes, which are all of growing interest in automotive, aerospace, building, or health applications.
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On the accuracy of monomer/polymer gel dosimetry in the proximity of a high-dose-rate 192Ir source
TL;DR: The aim of this work was to investigate the applicability of MR-based polymer gel dosimetry to measure the absorbed dose distribution at short distance from an iridium-192 brachytherapy point source by constructing a dose-versus-distance curve by polar averaging.
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Role of External Field in Polymerization: Mechanism and Kinetics.
TL;DR: This state-of-the-art research progress not only provides the fundamental principles underlying external-field-regulated polymerizations but also stimulates new development of advanced polymerization methods.
References
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Journal ArticleDOI
Kinetic approach of oxygen inhibition in ultraviolet- and laser-induced polymerizations
TL;DR: Influence de l'intensite de la lumiere sur la cinetique de polymerisation de systemes multi-acrylates is discussed in detail in this article.
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Real-time kinetic study of laser-induced polymerization
Christian Decker,Khalil Moussa +1 more
TL;DR: In this article, the photopolymerisation de formulations acryliques, a base of polyurethanne a groupes terminaux acrylate, de derive du MGEBA et de diluants reactifs acrylsiques (TMPTA, EDGA, HMMA), is discussed.
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Kinetic investigation of photopolymerizations induced by laser beams
Christian Decker,Khalil Moussa +1 more
TL;DR: In this article, real-time infrared (RTIR) spectroscopy was used to study the kinetics of polymerization of acrylic monomers exposed to the 337,4 nm continuous emission of a Kr+ laser.
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Photopolymerization Using Maleimides as Photoinitiators
TL;DR: The photo-initiated polymerization of 1,6-hexanedioldiacrylate (HDDA) has been investigated using a variety of N-substituted maleimides to initiate the polymerization process upon exposure to light from a mercury lamp as mentioned in this paper.