Kinetics of Atom Transfer Radical Polymerization
TLDR
In this paper, a review encompasses the fundamentals of kinetics of atom transfer radical polymerization (ATRP) and guidelines for synthesis of polymers with targeted architectures, predetermined molecular weights, narrow molecular weight distributions, and high retained chain end functionality are presented.About:
This article is published in European Polymer Journal.The article was published on 2017-04-01 and is currently open access. It has received 191 citations till now. The article focuses on the topics: Living free-radical polymerization & Atom-transfer radical-polymerization.read more
Citations
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Advanced Materials by Atom Transfer Radical Polymerization
TL;DR: Atom transfer radical polymerization (ATRP) has been successfully employed for the preparation of various advanced materials with controlled architecture as discussed by the authors, such as thermoplastic elastomers, nanostructured carbons, surfactants, dispersants, functionalized surfaces, and biorelated materials.
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Externally controlled atom transfer radical polymerization.
TL;DR: The aim of this review is to highlight the use of external regulations in ATRP and to summarize the state-of-the-art and future perspectives, focusing on mechanistic aspects, synthetic procedures, preparation of polymers with complex architectures and functional materials, and their applications.
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Atom Transfer Radical Polymerization: Billion Times More Active Catalysts and New Initiation Systems.
TL;DR: This perspective focuses on the relation between structure and activity of ATRP catalysts, and the consequent choice of the initiating system, which are paramount aspects to well-controlled polymerizations.
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Role of External Field in Polymerization: Mechanism and Kinetics.
TL;DR: This state-of-the-art research progress not only provides the fundamental principles underlying external-field-regulated polymerizations but also stimulates new development of advanced polymerization methods.
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Synthesis and Characterization of the Most Active Copper ATRP Catalyst Based on Tris[(4-dimethylaminopyridyl)methyl]amine.
Thomas G. Ribelli,Marco Fantin,Jean-Claude Daran,Kyle F. Augustine,Rinaldo Poli,Rinaldo Poli,Krzysztof Matyjaszewski +6 more
TL;DR: ATRP of methyl acrylate showed a well-controlled polymerization using as little as 10 ppm of catalyst relative to monomer, while side reactions such as CuI-catalyzed radical termination (CRT) could be suppressed due to the low concentration of L/CuI at a steady state.
References
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Living free-radical polymerization by reversible addition - Fragmentation chain transfer: The RAFT process
John Chiefari,Y. K. Chong,Frances Ercole,Julia Krstina,Justine Leigh Jeffery,Tam P. T. Le,Roshan T. A. Mayadunne,Gordon Francis Meijs,Catherine Louise Moad,Graeme Moad,Ezio Rizzardo,San H. Thang +11 more
TL;DR: The authors proposed a reversible additive-fragmentation chain transfer (RAFT) method for living free-radical polymerization, which can be used with a wide range of monomers and reaction conditions and in each case it provides controlled molecular weight polymers with very narrow polydispersities.
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Controlled/"living" radical polymerization. atom transfer radical polymerization in the presence of transition-metal complexes
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Polymerization of Methyl Methacrylate with the Carbon Tetrachloride/Dichlorotris- (triphenylphosphine)ruthenium(II)/Methylaluminum Bis(2,6-di-tert-butylphenoxide) Initiating System: Possibility of Living Radical Polymerization
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Atom Transfer Radical Polymerization (ATRP): Current Status and Future Perspectives
TL;DR: The current status and future perspectives in atom transfer radical polymerization (ATRP) are presented in this paper, with a special emphasis on mechanistic understanding of ATRP, recent synthetic and process development, and new controlled polymer architectures enabled by ATRP.