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Journal ArticleDOI

Layered Lithium Insertion Material of LiCo1/3Ni1/3Mn1/3O2 for Lithium-Ion Batteries

Tsutomu Ohzuku, +1 more
- 01 Jul 2001 - 
- Vol. 30, Iss: 7, pp 642-643
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TLDR
In this paper, LiCo1/3Ni 1/3Mn 1 /3O2 was prepared by a solid state reaction at 1000 °C in air and examined in nonaqueous lithium cells.
Abstract
Layered LiCo1/3Ni1/3Mn1/3O2 was prepared by a solid state reaction at 1000 °C in air and examined in nonaqueous lithium cells. LiCo1/3Ni1/3Mn1/3O2 showed a rechargeable capacity of 150 mAh g−1 in 3.5–4.2 V or 200 mAh g−1 in 3.5–5.0 V. Operating voltage of Li / LiCo1/3Ni1/3Mn1/3O2 was by 0.2–0.25 V lower than that of a cell with LiCoO2 or LiMn2O4 and by 0.15–0.3 V higher than that with LiNiO2 or LiCo1/2Ni1/2O2 due to a complex solid solution mechanism.

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Citations
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Towards greener and more sustainable batteries for electrical energy storage

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30 Years of Lithium-Ion Batteries.

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Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage

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References
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Journal ArticleDOI

LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density

TL;DR: In this paper, a new system LixCoO2 (0 Li x CoO 2 Li ) is proposed, which shows low overvoltages and good reversibility for current densities up to 4 mA cm−2 over a large range of x.
Journal ArticleDOI

Zero‐Strain Insertion Material of Li [ Li1 / 3Ti5 / 3 ] O 4 for Rechargeable Lithium Cells

TL;DR: In this paper, a defect spinel-framework structure was examined in nonaqueous lithium cells and it was shown that the lattice dimension did not change during the reaction since the reaction consists of lithium ion and electron insertion into/extraction from the solid matrix without a noticeable change in lattice dimensions.
Journal ArticleDOI

Lithium insertion into manganese spinels

TL;DR: In this article, Li has been inserted chemically and electrochemically into Mn3O4 and Li[Mn2]O4 at room temperature from X-ray diffraction.
Journal ArticleDOI

Electrochemistry and Structural Chemistry of LiNiO2 (R3̅m) for 4 Volt Secondary Lithium Cells

TL;DR: LiNiO[sub 2] was used for a 4 V secondary lithium cell in this paper, which exhibited more than 150 mAh/g of rechargeable capacity in the voltage range between 2.5 and 4.2 V in 1M LiClO(sub 4] propylene carbonate solution.
Journal ArticleDOI

Solid‐State Redox Reactions of LiCoO2 (R3̅m) for 4 Volt Secondary Lithium Cells

TL;DR: LiCoO[sub 2] (R[bar 3]m; a = 2.82 [angstrom], c = 14.1 [angström] in hexagonal setting) was prepared and examined in nonaqueous lithium cells using 1M LiClO [sub 4] propylene carbonate solution at 30 C as mentioned in this paper.
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