Mechanochemistry: New Tools to Navigate the Uncharted Territory of “Impossible” Reactions
Federico Cuccu,Lidia De Luca,Francesco Delogu,Evelina Colacino,Niclas Solin,Rita Mocci,Andrea Porcheddu +6 more
TLDR
In this paper , the reader is introduced to an intriguing research subject not yet fully explored and waiting for improved understanding, namely, organic transformations that, although impossible in solution, become possible under mechanochemical processing conditions, simultaneously entailing innovation and expanding the chemical space.Citations
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Mechanochemistry: New Tools to Navigate the Uncharted Territory of “Impossible” Reactions
Federico Cuccu,Lidia De Luca,Francesco Delogu,Evelina Colacino,Niclas Solin,Rita Mocci,Andrea Porcheddu +6 more
TL;DR: In this paper , the reader is introduced to an intriguing research subject not yet fully explored and waiting for improved understanding, namely, organic transformations that, although impossible in solution, become possible under mechanochemical processing conditions, simultaneously entailing innovation and expanding the chemical space.
Journal ArticleDOI
Minireview: Ni–Fe and Ni–Co Metal–Organic Frameworks for Electrocatalytic Water‐Splitting Reactions
TL;DR: In this article , the current state of research in Ni-based metal-organic frameworks (MOFs) as OER catalyst materials for alkaline electrolysis is presented, and strategies to improve the catalytic performance like compositional variations, choice of synthetic routes, and support materials are presented.
Journal ArticleDOI
Oxidation of alcohols using an oxoammonium salt bearing the nitrate anion
TL;DR: In this paper, a methodology for the oxidation of alcohols to the corresponding carbonyl compounds is reported using a sub-stoichiometric quantity of an oxoammonium salt bearing the nitrate counterion.
Journal ArticleDOI
Mechanochemical Approach for Air-Tolerant and Extremely Fast Lithium-Based Birch Reductions in Minutes.
TL;DR: In this paper , an ammonia-free lithium-based Birch reduction in air at room temperature without special operating conditions using a ball-milling technique was reported. But this method is characterized by its operational simplicity and an extremely short reaction time (within 1 min), probably owing to the in-situ mechanical activation of lithium metal.
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Mechanochemical preparation of edge-selectively hydroxylated graphene nanosheets using persulfate via a sulfate radical-mediated process.
TL;DR: In this paper , a mechanochemical reaction of graphite with persulfate solves the above drawback and produces edge-selectively hydroxylated graphene (EHG) nanosheets through a 2-h ball-milling and a subsequent 0.5-h sonication.
References
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Electric Field Effect in Atomically Thin Carbon Films
Kostya S. Novoselov,Andre K. Geim,Sergey V. Morozov,Da Jiang,Y. Zhang,S. V. Dubonos,Irina V. Grigorieva,A. A. Firsov +7 more
TL;DR: Monocrystalline graphitic films are found to be a two-dimensional semimetal with a tiny overlap between valence and conductance bands and they exhibit a strong ambipolar electric field effect.
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Hard and soft acids and bases
TL;DR: In this paper, the rate data for the generalized nucleophilic displacement reaction were reviewed, and the authors presented a method to estimate the rate of the generalized displacement reaction in terms of the number of nucleophiles.
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A Production of Amino Acids Under Possible Primitive Earth Conditions
TL;DR: In this study, an apparatus was built to circulate CHI4, NH3, H2O, and H2 past an electric discharge, and the resulting mixture has been tested for amino acids by paper chromatography.
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Mechanochemistry: opportunities for new and cleaner synthesis
Stuart L. James,Christopher J. Adams,Carsten Bolm,Dario Braga,Paul Collier,Tomislav Friščić,Fabrizia Grepioni,Kenneth D. M. Harris,Geoff Hyett,William Jones,Anke Krebs,James Mack,Lucia Maini,A. Guy Orpen,Ivan P. Parkin,William C. Shearouse,Jonathan W. Steed,Daniel C. Waddell +17 more
TL;DR: Concentrating on recent advances, this article covers industrial aspects, inorganic materials, organic synthesis, cocrystallisation, pharmaceutical aspects, metal complexes, supramolecular aspects and characterization methods.
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Organic Azides: An Exploding Diversity of a Unique Class of Compounds
TL;DR: In this Review, the fundamental characteristics of azide chemistry and current developments are presented and the focus will be placed on cycloadditions (Huisgen reaction), aza ylide chemistry, and the synthesis of heterocycles.