Journal ArticleDOI
Nanocrystalline copper(II) oxide catalyzed aza-Michael reaction and insertion of α-diazo compounds into N–H bonds of amines
TLDR
Nanocrystalline copper(II) oxide efficiently catalyzed the conjugate addition of aliphatic amines to α,β-unsaturated compounds to produce β-amino compounds with excellent yields under mild reaction conditions.About:
This article is published in Tetrahedron Letters.The article was published on 2009-08-05. It has received 256 citations till now. The article focuses on the topics: Diazo & Copper(II) oxide.read more
Citations
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Journal ArticleDOI
Oxidation by permanganate: synthetic and mechanistic aspects
TL;DR: In this article, alcohols and olefinic compounds undergo oxidation by permanganate through the formation of a substrate-Mn(VII) complex, which finally decomposes to give the desired products.
Book ChapterDOI
Synthesis in the key of Catellani: norbornene-mediated ortho C-H functionalization.
TL;DR: This review will primarily focus upon the mechanistic aspects of the Catellani reaction, followed by an overview of the synthetic scope of molecules currently accessible with this technology.
Book ChapterDOI
Pd-Catalyzed C–H Bond Functionalization on the Indole and Pyrrole Nucleus
TL;DR: This review details recent developments in the Pd-catalyzed C-H bond arylation and alkenylation of indoles and pyrroles, aromatic heterocycles that are frequently displayed in natural products and medicinal agents.
Journal ArticleDOI
TMPZnCl·LiCl: A New Active Selective Base for the Directed Zincation of Sensitive Aromatics and Heteroaromatics
Marc Mosrin,Paul Knochel +1 more
TL;DR: A wide range of polyfunctional aryl and heteroaryl zinc reagents were efficiently prepared in THF via direct zincation using TMPZnCl, a new exceptionally mild and efficient base.
References
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Journal ArticleDOI
Organic Synthesis with .alpha.-Diazo Carbonyl Compounds
Tao Ye,M. Anthony McKervey +1 more
Journal ArticleDOI
Catalytic methods for metal carbene transformations
TL;DR: Doyle et al. as discussed by the authors used transition-metal catalysts to generate transient electrophilic metal carhenes and achieved state-of-the-art performance on the Dreyfus Foundation Teacher-Scholar Award and Chemical Manufacturers Association Catalyst Award.
Journal ArticleDOI
Recent advances in the stereoselective synthesis of β-amino acids
Mei Liu,Mukund P. Sibi +1 more
Journal ArticleDOI
Bismuth Nitrate-Catalyzed Versatile Michael Reactions†
Neeta Srivastava,Bimal K. Banik +1 more
TL;DR: Bismuth nitrate-catalyzed versatile Michael reaction was developed to reduce the complications that characterize the current standard Michael reaction and used for facile preparation of organic compounds of widely different structures.
Journal ArticleDOI
Nanoparticle-supported and magnetically recoverable nickel catalyst: a robust and economic hydrogenation and transfer hydrogenation protocol
TL;DR: A magnetic nanoparticle-supported leach-proof Ni catalyst was readily prepared from inexpensive starting materials which catalyzes various hydrogenation and transfer hydrogenation reactions; high catalytic activity and ease of recovery using an external magnetic field are additional eco-friendly attributes of this catalytic system.
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