Journal ArticleDOI
New One-Pot Synthesis of (E)-β-Aryl Vinyl Halides from Styrenes
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TLDR
A new, efficient protocol for the highly stereoselective one-pot synthesis of (E)-beta-aryl vinyl iodides and (E-beta- Daryl vinyl bromides from styrenes based on sequential ruthenium-catalyzed silylative coupling-N-halosuccinimide-mediated halodesilylation reactions is reported.About:
This article is published in Organic Letters.The article was published on 2009-07-02. It has received 51 citations till now. The article focuses on the topics: Aryl & One-pot synthesis.read more
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Use of Bromine and Bromo-Organic Compounds in Organic Synthesis
TL;DR: The use of bromine and different bromo-organic compounds in organic synthesis is outlined and the scope of these reagents for various organic transformations such as bromination, cohalogenation, oxidation, cyclization, ring-opening reactions, substitution, rearrangement, hydrolysis, catalysis, etc is described briefly.
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General Copper‐Catalyzed Transformations of Functional Groups from Arylboronic Acids in Water
TL;DR: This study should provide a useful strategy for interconversions of the functional groups on aromatic rings in water under air.
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Direct synthesis of Z -alkenyl halides through catalytic cross-metathesis
TL;DR: It is shown that previously unknown halo-substituted molybdenum alkylidene species are exceptionally reactive and are able to participate in high-yielding olefin metathesis reactions that afford acyclic 1,2-disubstituting Z-alkenyl halides.
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Room Temperature Copper(II)-Catalyzed Oxidative Cyclization of Enamides to 2,5-Disubstituted Oxazoles via Vinylic C–H Functionalization
TL;DR: A copper-II-catalyzed oxidative cyclization of enamides to oxazoles via vinylic C-H bond functionalization at room temperature is described in this paper.
Direct synthesis of Z-alkenyl halides through catalytic cross-metathesis
TL;DR: In this paper, it was shown that Halo-substituted molybdenum alkylidene species are exceptionally reactive and are able to participate in high-yielding olefin metathesis reactions that afford acyclic 1,2-disubstitized Z-alkenyl halides.
References
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Stereochemical Control in Organic-Synthesis Using Silicon-Containing Compounds
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Simple and selective method for aldehydes (RCHO) .fwdarw. (E)-haloalkenes (RCH:CHX) conversion by means of a haloform-chromous chloride system
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Cover Picture: Shape‐Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics? (Angew. Chem. Int. Ed. 1/2009)
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Hydrozirconation: A New Transition Metal Reagent for Organic Synthesis
Jeffrey Schwartz,Jay A. Labinger +1 more
TL;DR: In this article, a procedure for functionalizing alkenes, alkynes, and 1,3-dienes via organozirconium(IV) intermediates is described.
Journal ArticleDOI
Catalysis by transition metal complexes of alkene silylation – recent progress and mechanistic implications
TL;DR: In this article, the mechanism of homogeneous catalysis for silylation of alkenes and silylalkynes with late transition metal complexes is discussed. But the authors focus on the synthesis of substituted vinyl-silicon functionalities.
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