Journal ArticleDOI
New synthetic pathways into the organometallic chemistry of gallium
TLDR
In this article, trasonic irradiation of gallium metal with di-iodine and alkyl iodides, RI, rapidly gives high yields of [RGaI2] via a reactive intermediate mate.About:
This article is published in Polyhedron.The article was published on 1990-01-01. It has received 138 citations till now. The article focuses on the topics: Gallium & Organometallic chemistry.read more
Citations
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N-heterocyclic carbene analogues with low-valent group 13 and group 14 elements: syntheses, structures, and reactivities of a new generation of multitalented ligands.
Journal ArticleDOI
Multiple bonding in heavier element compounds stabilized by bulky terphenyl ligands.
Eric Rivard,Philip P. Power +1 more
TL;DR: This paper summarizes recent developments involving the preparation and reactivity of molecular species stabilized by terphenyl ligands that feature new bonding environments that displays a 5-fold bonding interaction between the chromium centers.
Journal ArticleDOI
Structures, Bonding, and Reaction Chemistry of the Neutral Organogallium(I) Compounds (GaAr)n (n = 1 or 2) (Ar = Terphenyl or Related Ligand): An Experimental Investigation of Ga−Ga Multiple Bonding
TL;DR: The synthesis, structure, and properties of several new organogallium(I) compounds are reported, including one that featured almost linear gallium coordination, Ga-B distances near the sum of the covalent radii of gallium and boron, as well as some close Ga...F contacts.
Journal ArticleDOI
The reactivity of diazabutadienes toward low oxidation state Group 13 iodides and the synthesis of a new gallium(I) carbene analogue
TL;DR: In this paper, the reactions of two diazabutadiene ligands, Ar-DAB [(ArNCH)2, Ar = 2,6-Pri2C6H3] and But NCH 2, with either GaI or an AlI3/Al mixture have afforded the paramagnetic compounds, [{IGaII(But)-DAB] and [I2GaIII(But-DAb)] which have been characterised by X-ray crystallography and EPR spectroscopy.
Journal ArticleDOI
Low valent aluminum and gallium compounds — structural variety and coordination modes to transition metal fragments
G. Linti,H. Schnöckel +1 more
TL;DR: The chemistry of low valent aluminum and gallium compounds is a very topical area of research as discussed by the authors, which requires new insight on the description of chemical bonds, and not only the routes to these compounds and their structures described here, but thoughts on their description of bonding are presented as well.
References
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Journal ArticleDOI
ULTRASOUND: Its Chemical, Physical and Biological Effects
Book
Gmelin handbook of inorganic chemistry
Ekkehard Fluck,Leopold Gmelin,R. J. Meyer,Erich Pietsch,Alfons Kotowski,Margot Becke‐Goehring,Marie-Louise Gerwien,Rudolf Warncke,Rainer Bohrer,Gottfried Olbrich,Helga Hartwig +10 more
TL;DR: The Gmelin Formula Index is updated by inclusion of the volumes which appeared up to the end of 1987, and all compounds described in the GMelin Handbook of Inorganic Chemistry in the period between 1924 and 1987 can be located.
Journal ArticleDOI
Eigenschaften und Strukturen reduzierter Galliumiodide: Ga2I4 und Ga2I3
TL;DR: In this article, the crystal structures of reduced gallium halides have been investigated using diffractometer data, and the most metal-rich gallium iodide, Ga2I4, has been shown to have a tube-like arrangement of tetrahedra.
Journal ArticleDOI
Crystal and molecular structure of the tetrahydrofuran adduct of (vinylgallium)tetracarbonyliron, [(THF)(C2H3)GaFe(CO)4]2: comparison with isoelectronic zinc and germanium dimers
Journal ArticleDOI
Phase studies of the InCl and GaI systems
TL;DR: In this article, it was suggested that the structure of these three compounds are In(I) [In(III)Cl4], [Ga(I)]2 [Ga (III)I5] and [Ga[I]3 [Ga-III]I6] respectively.