Journal ArticleDOI
Nickel(0)-Mediated Intramolecular Cyclizations of Enynes, Dienynes, Bis-Dienes, and Diynes
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This article is published in Synlett.The article was published on 1992-01-01. It has received 82 citations till now. The article focuses on the topics: Intramolecular reaction & Intramolecular force.read more
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Journal ArticleDOI
Recent Advances in the Pauson–Khand Reaction and Related [2+2+1] Cycloadditions
Kay M. Brummond,Joseph L. Kent +1 more
TL;DR: The Pauson-Khand reaction has been studied extensively in the literature as discussed by the authors, with a focus on cycloaddition precursors for natural product synthesis, such as dicobaltoctacarbonyl and traceless tethers.
Journal ArticleDOI
Selective Preparation of Complex Polycyclic Molecules from Acyclic Precursors via Radical Mediated- or Transition Metal-Catalyzed Cascade Reactions.
Journal ArticleDOI
New Developments in the Pauson-Khand Reaction.
Oliver Geis,Hans-Günther Schmalz +1 more
TL;DR: Catalytic and asymmetric variations, enones, enynes, and allene as other starting materials, and numerous applications in natural product synthesis are all evidence of the diversity of the Pauson-Khand reaction, which now definitely counts among the standard tools of organic synthesis.
Book ChapterDOI
A Review of Recent Progress in Catalyzed Homogeneous Hydrosilation (Hydrosilylation)
TL;DR: In this paper, a new type of Fe(0) complex, containing a diimine-based pincer ligand and two coordinated dinitrogen molecules has been shown to be an effective and, remarkably, regiospecific catalyst for the hydrosilation of a variety of terminal alkenes with PhSiH3 or Ph2SiH2.