Journal ArticleDOI
On the mechanism of the formation of s(−)-(1, 1'-binaphthalene)-2,2'-diol via copper(II)amine complexes
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In this article, the oxidative dimerization of 2-naphthol was studied by means with several copper(II)amine complexes as oxidants using primary amines.About:
This article is published in Tetrahedron.The article was published on 1985-01-01. It has received 149 citations till now. The article focuses on the topics: Racemization & Amine gas treating.read more
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Aerobic Copper-Catalyzed Organic Reactions
TL;DR: The chemistry of copper is extremely rich because it can easily access Cu0, CuI, CuII, and CuIII oxidation states allowing it to act through one-electron or two-Electron processes, which feature confer a remarkably broad range of activities allowing copper to catalyze the oxidation and oxidative union of many substrates.
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Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity
TL;DR: This critical review discusses historical and contemporary research in the field of transition metal-catalyzed carbon-hydrogen (C-H) bond activation through the lens of stereoselectivity, placing an emphasis on reactions that are (or may soon become) relevant in the realm of organic synthesis.
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Copper-Catalyzed Aerobic Oxidative C ? H Functionalizations: Trends and Mechanistic Insights
TL;DR: This work has reported several recently reported Cu-catalyzed C-H oxidation reactions that feature substrates that are electron-deficient or appear unlikely to undergo single-electron transfer to copper(II), and evidence has been obtained for the involvement of organocopper(III) intermediates in the reaction mechanism.
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Atroposelective Synthesis of Axially Chiral Biaryl Compounds
Gerhard Bringmann,Anne J. Price Mortimer,Paul A. Keller,Mary J. Gresser,James Garner,Matthias Breuning +5 more
TL;DR: This Review classifies strategies in the asymmetric synthesis of axially chiral biaryl compounds according to their underlying concepts and critically evaluates their scope and limitations with reference to selected model reactions and applications.
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Oxidative C-H/C-H Coupling Reactions between Two (Hetero)arenes.
TL;DR: This review provides a comprehensive overview of the fundamentals and applications of transition metal-mediated/catalyzed oxidative C-H/C-H coupling reactions between two (hetero)arenes.
References
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Design of complexes between synthetic hosts and organic guests
Donald J. Cram,Jane M. Cram +1 more
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Chiral recognition in molecular complexing
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Host-guest complexation. 12. Total optical resolution of amine and amino ester salts by chromatography
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Enantioselective synthesis of binaphthyls via nucleophilic aromatic substitution on chiral oxazolines
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Biomimetic asymmetric oxidative coupling of phenols
Bernard Feringa,Hans Wynberg +1 more
TL;DR: In this paper, the first examples of asymmetric induction in the oxidative coupling of phenols using chiral oxidants were described, and they were used as oxidants for the formation of optically active d-dehydrogriseofulvin and l -Licarin A.