Book ChapterDOI
Organometallic Oxometal Clusters
TLDR
In this paper, structural relationships, structural preferences, and stereochemical non-rigidity of organometallic oxometal clusters are discussed in connection with those of polyoxo(alkoxo)metalates and organometalloys.Abstract:
The presentation focusses on integrated oxometal clusters containing fac-{M(CO)3}+ (M = Mn, Re), {Rh(η5-C5Me5)2+ or {Ru(η6-arene)}2+ organometallic subunits and oxo(alkoxo)molybdenum or tungsten subunits. The discussion adresses the following questions: i) structural relationships, ii) structural preferences, and iii) stereochemical non-rigidity. The molecular structures of the organometallic oxometal clusters are discussed in connection with those of previously reported polyoxo(alkoxo)metalates and organometallic clusters. The apparent structural relationships within these clusters underscore the electronic connection between d6-fac-{ML3} (M = Mn, Re, Ru, Rh,) and d0-fac-{MO3} or d0-fac-{MO2(OR)}+ (M = Mo, W) units.read more
Citations
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Journal ArticleDOI
Polyoxometalates: introduction to a class of inorganic compounds and their biomedical applications.
TL;DR: The reported antitumoral and antibiotic properties of molybdates and tungstates in vitro and in vivo are compiled and discussed, as are their influences on the blood glucose level in diabetic animals.
Journal ArticleDOI
Applications of Polyoxometalates (A Review)
TL;DR: A wholesome outline of polyoxometalates has been attempted encompassing their diverse nature owing to their structure and scope of application as mentioned in this paper , which function as anti-cancer, anti-bacterial and anti-viral drugs as well.
Dissertation
Incorporation of pyramidal heteroanions in mixed-metal polyoxometalate based cages
TL;DR: In this paper, the authors propose a solution to solve the problem of the problem: this paper...,.. ].. ).. ;. ] ].
References
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BookDOI
Polyoxometalates : from platonic solids to anti-retroviral activity
Michael T. Pope,Achim Müller +1 more
TL;DR: Polyoxometalates: A Class of Compounds with Remarkable Topology as discussed by the authors, a class of compounds with remarkable topology, have been shown to have remarkable properties.
Journal ArticleDOI
Main-Group Element, Organic, and Organometallic Derivatives of Polyoxometalates.
Pierre Gouzerh,Anna Proust +1 more
Journal ArticleDOI
Metal Oxide Chemistry in Solution: The Early Transition Metal Polyoxoanions
TL;DR: Systematic studies of small polyoxoanions in inert, aprotic solvents have clarified many of the principles governing their structure and reactivity, and have made possible the preparation of entirely new types of covalent derivatives.
Journal ArticleDOI
Trisubstituted heteropolytungstates as soluble metal oxide analogs. 1. The preparation, characterization, and reactions of organic solvent soluble forms of the silicon-niobium heteropolytungstates Si2W18Nb6O778-, SiW9Nb3O407-, and the SiW9Nb3O407- supported organometallic complex [(C5Me5)Rh.cntdot.SiW9Nb3O40]5-
Richard G. Finke,Michael Droege +1 more