Journal ArticleDOI
Oscillations during electrolysis of alkaline iodide + iodate solutions
E.V. Radkov,L.G. Ljutov +1 more
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This article is published in Journal of Electroanalytical Chemistry.The article was published on 1988-02-10. It has received 9 citations till now. The article focuses on the topics: Iodate & Potassium iodate.read more
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Journal ArticleDOI
Electrochemical Reaction Dynamics - A Review
TL;DR: In this paper, the status of research on the dynamics of electrochemical reactions is reviewed, including the electrodissolution of metals, cathodic deposition, and electrocatalytic reactions.
Journal ArticleDOI
Potential Oscillations during the Electrocatalytic Oxidation of Sulfide on a Microstructured Ti/Ta2O5-IrO2 Electrode
Aicheng Chen and,Brad Miller +1 more
TL;DR: In this paper, two distinct galvanostatic potential oscillations were observed during the electrooxidation of sulfide on an oxide electrode and the features of the potential oscillation strongly depend on the applied current densities.
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Modeling galvanostatic potential oscillations in the electrocatalytic iodate reduction system
TL;DR: In this article, an experimental and theoretical description of the oscillatory electrocatalytic iodate reduction system in alkaline solution is presented, and the dynamical behavior of the model compares favorably with experiments as far as voltammetric profiles, stirring effects and bifurcations between stable and oscillatory states are concerned.
Journal ArticleDOI
Further insight into the origin of potential oscillations during the iodate reduction in alkaline solution with mass transfer
TL;DR: In this paper, the authors used in situ Raman spectroscopy to demonstrate that the electrochemical reactions, i.e., iodate reduction and periodic hydrogen evolution, coupled with alternately predominant diffusion and convection mass transfer, account for the potential oscillation that appears under galvanostatic reduction of iodate over its limiting current in alkaline solution.
Journal ArticleDOI
New insight into the potential oscillations during iodate reduction in alkaline solution
Zelin Li,Jiale Cai,Shaomin Zhou +2 more
TL;DR: In this article, the potential oscillations during the reduction of iodate ions in alkaline solution under galvanostatic conditions have been re-investigated without adding iodide, and it was shown that the oscillations can take place only when the applied current is larger than the limiting current, and the oscillation amplitudes are within the plateau region of the limiting currents.
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