Journal ArticleDOI
Picosecond pulse radiolysis—VI. Fast electron reactions in concentrated solutions of scavengers in water and alcohols
TLDR
In this paper, the initial yield of solvated electrons in all solvents studied was reduced in the presence of a high concentration of scavengers, and exhibited a semilogarithmic dependence on the scavenger concentration.About:
This article is published in International Journal for Radiation Physics and Chemistry.The article was published on 1975-04-01. It has received 99 citations till now. The article focuses on the topics: Reaction rate constant & Solvated electron.read more
Citations
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Radiation Chemistry in Chemically Amplified Resists
Takahiro Kozawa,Seiichi Tagawa +1 more
TL;DR: In this article, the authors review the radiation chemistry of materials related to chemically amplified resist materials and discuss the imaging mechanisms from energy deposition to proton migration in resist materials are discussed.
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Dependence of Molecular Hydrogen Formation in Water on Scavengers of the Precursor to the Hydrated Electron
TL;DR: In this paper, the authors show that the previously accepted nonscavengable yield of molecular hydrogen is due to precursors of the hydrated electron and it can be lowered with appropriate scavengers.
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Radiolysis effects in muonium chemistry
TL;DR: In this paper, the chemistry of muonium, a light isotope of hydrogen, is investigated for the time period immediately after stopping of its precursor, the positive muon, in the condensed phase.
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Electron and hole transport to trap groups at the ends of conjugated polyfluorenes.
TL;DR: From observations, electron mobilities for transport along single chains to the end caps in THF solution were determined to be smaller by a factor of 100 than those observed by microwave conductivity, but the mobilities were sufficiently large to provide encouragement to the use of such single chains in solar photovoltaics.
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Reducing Radicals in Nitrate Solutions. The NO32- System Revisited
Andrew R. Cook,Nada Dimitrijevic,Benjamin W. Dreyfus,Dan Meisel,Larry A. Curtiss,D. Camaioni +5 more
TL;DR: In this article, the one-electron reduction product of nitrate, the NO{sub 3} radical, was reinvestigated because of the contemporary interest in its reactivity in high-level liquid radioactive systems.
References
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Journal ArticleDOI
Theory of Radiation Chemistry. II. Track Effects in Radiolysis of Water
Aryeh H. Samuel,John L. Magee +1 more
TL;DR: In this article, a model for the geometrical effects in the radiolysis of water as a result of the diffusion of free radicals is presented, and the motion of secondary electrons immediately following the passage of the ionizing particle is discussed in an appendix.
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Applications of the spur diffusion model to the radiation chemistry of aqueous solutions
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Scavenging Kinetics of Electrons Produced by Irradiation of Organic Glasses; Experimental Evidence for Long Range Tunneling
TL;DR: In this paper, the influence of scavengers on the yields of trapped electrons in γ-irradiated organic glasses was investigated, and it was shown that trapped electron yields observed minutes after irradiation decrease exponentially with scavenger concentration.
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Picosecond pulse radiolysis studies. ii. reactions of electrons with concentrated scavengers.
TL;DR: In this article, the decay of solvated electrons in various aqueous solutions was studied using a stroboscopic pulse radiolysis technique with a time resolution of 24 psec.