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Piezoelectric and mechanical behavior of NaNbO3/PEKK lead-free nanocomposites

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TLDR
In this paper, lead-free piezoelectric nanocomposites based on poly(ether ketone ketone) (PEKK) and sodium niobate (NaNbO3) particles were elaborated.
Abstract
Lead-free piezoelectric nanocomposites based on poly(ether ketone ketone) (PEKK) and sodium niobate (NaNbO3) particles were elaborated. The presence of submicronic particles does not influence the thermal stability of the matrix so that no degradation phenomenon is observed before 500 °C. The conservative mechanical modulus G′ increases linearly with the NaNbO3 fraction; this variation is well fitted by the Kerner model until 20 vol%. Such nanocomposites remain ductile. The polarizing field required for obtaining piezoelectric nanocomposites is 12 kV·mm−1 i.e. analogous with the one used for poling bulk ceramic. The value of the piezoelectric coefficient (d33 = 0.2 pC·N−-1 for 20 vol% NaNbO3) is consistent with the Furukawa's model. This value is explained by the low PEKK permittivity. This low d33 is counterbalanced by the piezoelectric voltage constant (g33 = 103·10−3 Vm·N−1) which is higher than the one of classical piezoelectric ceramic like PZT or BaTiO3.

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Citations
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Journal ArticleDOI

Electrode Materials for Supercapacitors: A Review of Recent Advances

TL;DR: In this paper, a review describes the insights of the recent electrode materials (including, carbon-based materials, metal oxide/hydroxide based materials, and conducting polymer-based material, 2D materials).
Journal ArticleDOI

Electrical behavior of a graphene/PEKK and carbon black/PEKK nanocomposites in the vicinity of the percolation threshold

TL;DR: In this article, a simple exfoliation protocol to obtain graphene monolayers has led to a significant decrease of the percolation threshold from 4.2 to 1.9 vol%.
Journal ArticleDOI

Effect of PEKK oligomers sizing on the dynamic mechanical behavior of poly(ether ketone ketone)/carbon fiber composites

TL;DR: In this paper, a PEKK oligomer (PEKKo) sizing with a chemical compatibility with PEKK is proposed for promoting interfacial interactions in order to enhance mechanical performances.
Journal ArticleDOI

Piezoelectric biosensor for smart cardiovascular grafts based on NaNbO3 fibers / PDMS structured composite

TL;DR: In this article , a biocompatible piezocomposite is designed for self-monitoring smart vascular grafts, which can recognize the presence of clots and prevent graft performance deterioration.
Patent

Piezoelectric polyether-ether-ketone composite material with antibacterial properties, and preparation method and application thereof

TL;DR: In this article, a piezoelectric polyether-ether-ketone/ niobate composite fiber material was obtained by the following steps that: polyether andether-etone and Niobate are blended after being dried, at a temperature of 350-450DEG C.
References
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Journal ArticleDOI

Connectivity and piezoelectric-pyroelectric composites

TL;DR: In this article, a series and parallel model for composite piezoelectric and pyroelectrics is presented, which leads to several interesting results, such as a diphasic pyroelectric in which neither phase is pyrocharged.
Journal ArticleDOI

The Elastic and Thermo-elastic Properties of Composite Media

TL;DR: In this article, the gross bulk and shear moduli of a composite material consisting of a suspension of grains or a compact of grains are derived from an analysis of the dilatation and bulk stress for average spherical grains when the composite as a whole is subjected to some small temperature change.
Journal ArticleDOI

Piezoelectric properties in the composite systems of polymers and PZT ceramics

TL;DR: In this paper, the authors studied the piezoelectric properties of PZT ceramics and polymers including polyvinylidene fluoride (PVDF), polyethylene (PE), and polyvinylon alcohol (PVA).
Journal ArticleDOI

Dielectric and piezoelectric properties of PVDF/PZT composites: A review

TL;DR: In this paper, the effect of grain size, content and other factors under the purview of dielectric and piezoelectric properties while evaluating the sensitivity of the material for sensor application was evaluated.
Journal ArticleDOI

Electromechanical Properties in the Composites of Epoxy Resin and PZT Ceramics

TL;DR: In this article, the complex dielectric, elastic and piezoelectric constants were measured for composites of epoxy resin and ferroelectric PZT ceramics at 10 Hz as a function of temperature, and the magnitudes and loss tangents of these constants were compared with the theoretical predictions.
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