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Journal ArticleDOI

Plasmonics—A Route to Nanoscale Optical Devices

TLDR
In this paper, a point dipole analysis predicts group velocities of energy transport that exceed 0.1c along straight arrays and shows that energy transmission and switching through chain networks such as corners and tee structures is possible at high efficiencies.
Abstract
The further integration of optical devices will require the fabrication of waveguides for electromagnetic energy below the diffraction limit of light. We investigate the possibility of using arrays of closely spaced metal nanoparticles for this purpose. Coupling between adjacent particles sets up coupled plasmon modes that give rise to coherent propagation of energy along the array. A point dipole analysis predicts group velocities of energy transport that exceed 0.1c along straight arrays and shows that energy transmission and switching through chain networks such as corners (see Figure) and tee structures is possible at high efficiencies. Radiation losses into the far field are expected to be negligible due to the near-field nature of the coupling, and resistive heating leads to transmission losses of about 6 dB/lm for gold and silver particles. We analyze macroscopic analogues operating in the microwave regime consisting of closely spaced metal rods by experiments and full field electrodynamic simulations. The guiding structures show a high confinement of the electromagnetic energy and allow for highly variable geometries and switching. Also, we have fabricated gold nanoparticle arrays using electron beam lithography and atomic force microscopy manipulation. These plasmon waveguides and switches could be the smallest devices with optical functionality.

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Book

Plasmonics: Fundamentals and Applications

TL;DR: In this paper, the authors discuss the role of surface plasmon polaritons at metal/insulator interfaces and their application in the propagation of surfaceplasmon waveguides.
Journal ArticleDOI

Chemistry and properties of nanocrystals of different shapes.

TL;DR: The interest in nanoscale materials stems from the fact that new properties are acquired at this length scale and, equally important, that these properties are equally important.
Journal ArticleDOI

Shape-Controlled Synthesis of Gold and Silver Nanoparticles

TL;DR: Monodisperse samples of silver nanocubes were synthesized in large quantities by reducing silver nitrate with ethylene glycol in the presence of poly(vinyl pyrrolidone) (PVP), characterized by a slightly truncated shape bounded by {100, {110}, and {111} facets.
Journal ArticleDOI

Shape‐Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics?

TL;DR: A comprehensive review of current research activities that center on the shape-controlled synthesis of metal nanocrystals, including a brief introduction to nucleation and growth within the context of metal Nanocrystal synthesis, followed by a discussion of the possible shapes that aMetal nanocrystal might take under different conditions.
Journal ArticleDOI

Anisotropic metal nanoparticles: Synthesis, assembly, and optical applications

TL;DR: Variations in reaction conditions and crystallographic analysis of gold nanorod have led to insight into the growth mechanism of these materials, and optical applications in sensing and imaging, which take advantage of the visible light absorption and scattering properties of the nanorods are discussed.
References
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Book

Optical Properties of Metal Clusters

TL;DR: In this paper, the authors present a survey of optical spectra of Elemental Metal Clusters and Chain Aggregates and discuss experimental results and experimental methods for metal clustering experiments.
Book

Fundamentals of Photonics

TL;DR: The Fundamentals of Photonics, Third Edition as discussed by the authors is a self-contained and up-to-date introductory-level textbook that thoroughly surveys this rapidly expanding area of engineering and applied physics.
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