Journal ArticleDOI
Polymer Networks Assembled by Host−Guest Inclusion between Adamantyl and β-Cyclodextrin Substituents on Poly(acrylic acid) in Aqueous Solution
Li Li,Xuhong Guo,Jie Wang,Peng Liu,Robert K. Prud'homme,Bruce Lindley May,Stephen F. Lincoln +6 more
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TLDR
In this paper, the authors studied the host-guest interactions between β-cyclodextrin (β-CD) and 1-(2-aminoethyl)amidoadmantyl (ADen) substituents on poly(acrylic acid) (PAA).Abstract:
Polymer networks have been constructed through host−guest inclusion between β-cyclodextrin (β-CD) and 1-(2-aminoethyl)amidoadmantyl (ADen) substituents on poly(acrylic acid) (PAA). The structure of the networks and the host−guest interactions between the β-CD and ADen groups were studied by rheology and 2D 1H NOESY NMR spectroscopy. The maximum viscosity of the mixture of β-CD substituted PAA (β-CDPAA) and ADen substituted PAA (ADenPAA) occurred at a 1:1 β-CD:ADen substituent ratio which confirmed their binary inclusion. The viscosity of the mixture of the two polymers decreased upon addition of native β-CD due to its ability to compete favorably with the β-CD substituents of β-CDPAA in the inclusion of the ADen substituents of ADenPAA and the consequent disintegration of the polymer network. The rheological properties of the polymer networks were temperature sensitive. In the temperature range 10−35 °C, the storage modulus and the loss modulus obeyed a time−temperature superposition. The horizontal and v...read more
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25th Anniversary Article: Engineering Hydrogels for Biofabrication
Jos Malda,Jos Malda,Jetze Visser,Ferry P.W. Melchels,Ferry P.W. Melchels,Tomasz Jungst,Wim E. Hennink,Wouter J.A. Dhert,Jürgen Groll,Dietmar W. Hutmacher,Dietmar W. Hutmacher +10 more
TL;DR: This review focuses on the deposition process, the parameters and demands of hydrogels in biofabrication, with special attention to robotic dispensing as an approach that generates constructs of clinically relevant dimensions.
Journal ArticleDOI
Supramolecular polymeric materials via cyclodextrin-guest interactions.
TL;DR: This Account demonstrates some of the great advances in the development of supramolecular materials through host-guest interactions within the last 10 years, and uses the molecular recognition of CDs to achieve macroscopic self-assemblies, and this chemistry can direct these macroscopy objects into even larger aggregated structures.
Journal ArticleDOI
Cyclodextrin-based polymeric materials: synthesis, properties, and pharmaceutical/biomedical applications.
TL;DR: This review describes the synthesis, properties, and, in particular, biomedical and pharmaceutical applications of an upcoming class of polymeric networks and assemblies based on cyclodextrins (CDs).
Journal ArticleDOI
Highly Flexible, Tough, and Self-Healing Supramolecular Polymeric Materials Using Host-Guest Interaction
TL;DR: A supramolecular polymeric material using multipoint molecular recognition between cyclodextrin and hydrophobic guest molecules at polymer side chain is reported and a transparent, flexible, and tough hydrogel (host-guest gel) is formed by a simple preparation procedure.
Journal ArticleDOI
Preparation of water-soluble β-cyclodextrin/poly(acrylic acid)/graphene oxide nanocomposites as new adsorbents to remove cationic dyes from aqueous solutions
TL;DR: In this paper, β-cyclodextrin/poly(acrylic acid) grafted onto graphene oxide (β-CD/PAA/GO) was successfully synthesized for the first time using an esterification reaction, and they were used to remove the cationic dyes methylene blue (MB) and safranine T (ST) from aqueous solutions.
References
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Journal ArticleDOI
Cyclodextrin inclusion complexes: studies of the variation in the size of alicyclic guests
Journal ArticleDOI
Cyclodextrin-Modified Polyethylenimine Polymers for Gene Delivery
Suzie H. Pun,Nathalie C. Bellocq,Aijie Liu,Greg Jensen,Todd Machemer,Erlinda Quijano,Thomas Schluep,Shu-Fen Wen,Heidrun Engler,Jeremy D. Heidel,Mark E. Davis +10 more
TL;DR: Tail vein injections into mice of 120 microg of plasmid DNA formulated with CD-lPEI and AD-PEG do not reveal observable toxicities, and both nucleic acid accumulation and expression are observed in liver.
Journal ArticleDOI
Supramolecular Layer-by-Layer Assembly: Alternating Adsorptions of Guest- and Host-Functionalized Molecules and Particles Using Multivalent Supramolecular Interactions
TL;DR: The stepwise construction of a novel kind of self-assembled organic/inorganic multilayer films based on multivalent supramolecular interactions between guest-functionalized dendrimers and host-modified gold nanoparticles has been developed, yielding supramolescular layer-by-layer assembly.
Journal ArticleDOI
Construction of Supramolecular Polymers with Alternating α-, β-Cyclodextrin Units Using Conformational Change Induced by Competitive Guests
Masahiko Miyauchi,Akira Harada +1 more
TL;DR: In this paper, the first example of construction of supramolecular polymers with alternating α-, β-cyclodextrin units was presented, where a mixture of an α-CD and a β-CD derivative formed intermolecular complexes to give alternating CD units.
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