Journal ArticleDOI
Polymeric Schiff Bases as Low‐Voltage Redox Centers for Sodium‐Ion Batteries
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TLDR
Electroactive polymeric Schiff bases were produced by reaction between non-conjugated aliphatic or conjugated aromatic diamine block with terephthalaldehyde unit, able to electrochemically store more than one sodium atom per azomethine group.Abstract:
The redox entity comprising two Schiff base groups attached to a phenyl ring (NCHArHCN) is reported to be active for sodium-ion storage (Ar=aromatic group) Electroactive polymeric Schiff bases were produced by reaction between non-conjugated aliphatic or conjugated aromatic diamine block with terephthalaldehyde unit Crystalline polymeric Schiff bases are able to electrochemically store more than one sodium atom per azomethine group at potentials between 0 and 15 V versus Na+/Na The redox potential can be tuned through conjugation of the polymeric chain and by electron injection from donor substituents in the aromatic rings Reversible capacities of up to 350 mA h g−1 are achieved when the carbon mixture is optimized with Ketjen Black Interestingly, the “reverse” configuration (CHNArNHC) is not electrochemically active, though isoelectronicread more
Citations
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Journal ArticleDOI
Research Development on Sodium-Ion Batteries
Naoaki Yabuuchi,Kei Kubota,Kei Kubota,Mouad Dahbi,Mouad Dahbi,Shinichi Komaba,Shinichi Komaba +6 more
Journal ArticleDOI
Sodium-ion batteries: present and future
TL;DR: Current research on materials is summarized and discussed and future directions for SIBs are proposed to provide important insights into scientific and practical issues in the development of S IBs.
Journal ArticleDOI
Recent Progress in Electrode Materials for Sodium-Ion Batteries
Hyungsub Kim,Haegyeom Kim,Haegyeom Kim,Zhang Ding,Zhang Ding,Myeong Hwan Lee,Kyungmi Lim,Gabin Yoon,Kisuk Kang +8 more
TL;DR: In this paper, a review of recent progress on electrode materials for NIBs, including the discovery of new electrode materials and their Na storage mechanisms, is briefly reviewed, and efforts to enhance the electrochemical properties of NIB electrode materials as well as the challenges and perspectives involving these materials are discussed.
Journal ArticleDOI
Electrolyte design strategies and research progress for room-temperature sodium-ion batteries
Haiying Che,Suli Chen,Yingying Xie,Yingying Xie,Hong Wang,Khalil Amine,Xiao-Zhen Liao,Zi-Feng Ma +7 more
TL;DR: In this article, a review of electrolyte design strategies for various materials systems as well as functional applications is presented, where the discussion is divided into three electrolyte types: liquid, solid state, and gel state.
Journal ArticleDOI
Opportunities and Challenges for Organic Electrodes in Electrochemical Energy Storage.
TL;DR: This review provides a comprehensive overview of all reported cell configurations that involve electroactive organic compounds working either in the solid state or in solution for aqueous or nonaqueous electrolytes and highlights the most promising systems based on such various chemistries.
References
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Building better batteries
TL;DR: Researchers must find a sustainable way of providing the power their modern lifestyles demand to ensure the continued existence of clean energy sources.
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Electrochemical Energy Storage for Green Grid
Zhenguo Yang,Jianlu Zhang,Michael Kintner-Meyer,Xiaochuan Lu,Daiwon Choi,John P. Lemmon,Jun Liu +6 more
TL;DR: This review offers details of the technologies, in terms of needs, status, challenges and future R&d directions, that are expected to integrate significant levels of renewables into the electrical grid.
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Towards sustainable and versatile energy storage devices: an overview of organic electrode materials
TL;DR: In this paper, an overview of organic electrode materials, including their fundamental knowledge, development history and perspective applications, is provided. And the authors elaborate in detail various organics with different structures, including conducting polymers, organodisulfides, thioethers, nitroxyl radical polymers and conjugated carbonyl compounds.
Journal ArticleDOI
Update on Na-based battery materials. A growing research path
TL;DR: In this paper, the feasibility of two novel energy storage systems: Na-aqueous batteries and Na-O2 technology is explored, and new advances on nonaqueous Na-ion systems are summarized.
Journal ArticleDOI
Conjugated dicarboxylate anodes for Li-ion batteries.
Michel Armand,Sylvie Grugeon,Hervé Vezin,Stéphane Laruelle,Périnne Ribière,Philippe Poizot,Jean-Marie Tarascon +6 more
TL;DR: Two organic salts, Li(2)C(8)H(4)O(4), with carboxylate groups conjugated within the molecular core, with enhanced thermal stability over carbon electrodes in 1 M LiPF(6) ethylene carbonate-dimethyl carbonate electrolytes, which should result in safer Li-ion cells.