Journal ArticleDOI
Prediction of the glass transition temperature of polymers
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In this article, a method for predicting the glass transition temperature of polymers from the chemical structure was proposed, which uses increments for constitutional molecule groups and the found increments appear to correlate with the increments to the molar cohesion energy.About:
This article is published in Polymer.The article was published on 1970-02-01. It has received 60 citations till now. The article focuses on the topics: Glass transition & Cohesion (chemistry).read more
Citations
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Journal ArticleDOI
Glass transition and phase state of organic compounds: dependency on molecular properties and implications for secondary organic aerosols in the atmosphere.
TL;DR: Estimates for the glass forming properties of atmospheric secondary organic aerosol (SOA) are presented and how the viscosity in liquid, semi-solid and glassy states affect the diffusivity of those molecules constituting the organic matrix are shown.
Book ChapterDOI
Using Molecular Simulation to Predict the Physical and Mechanical Properties of Polybenzoxazines
TL;DR: This chapter addresses the simulation of the structures and selected properties of a series of benzoxazine monomers and polymers that are the focus of several research programs and explores polymer chemistry, which is adept at producing a wide range of polymeric materials tailored to a variety of applications.
Journal ArticleDOI
Structure-properties relationships for densely cross-linked epoxide-amine systems based on epoxide or amine mixtures
TL;DR: In this paper, the solubility and diffusivity of water at 100°C, 95% relative humidity were studied for 14 stoichiometric epoxide-amine networks based on epoxide or amine mixtures.
Journal ArticleDOI
Scoping the polymer genome: A roadmap for rational polymer dielectrics design and beyond
Arun Mannodi-Kanakkithodi,Arun Mannodi-Kanakkithodi,Anand Chandrasekaran,Chiho Kim,Tran Doan Huan,Ghanshyam Pilania,Ghanshyam Pilania,Venkatesh Botu,Rampi Ramprasad +8 more
TL;DR: By scoping the polymer genome, this work presents an essential roadmap for the design of polymer dielectrics, and provides future perspectives and directions for expansions to other polymer subclasses and properties.
Journal ArticleDOI
Quantitative Structure−Property Relationship (QSPR) Correlation of Glass Transition Temperatures of High Molecular Weight Polymers
TL;DR: A new quantitative structure−property relationship (QSPR) five-parameter correlation of molar glass transition temperatures (Tg/M) for a diverse set of 88 polymers is developed with the Comprehensive Descriptors for Structural and Statistical Analysis (CODESSA) program.
References
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Journal ArticleDOI
The relationship between glass temperature, molar cohesion, and polymer structure
TL;DR: An empirical equation relating glass temperature, molar cohesion, and polymer structure has been developed from data found in the literature as discussed by the authors, where a fairly extensive list of group cohesion values has been obtained from this relationship and glass temperatures which are in good agreement with reported values have been calculated.
BookDOI
Physical constants of linear homopolymers
TL;DR: This book will not become a unity of the way for you to get amazing benefits at all, but, it will serve something that will let you get the best time and moment to spend for reading the book.
Journal ArticleDOI
Influence of cohesive forces on the glass transition temperatures of polymers
W. A. Lee,J. H. Sewell +1 more
TL;DR: The relationship between cohesive energy (c.e.d) and the glass transition tenperature (Tg) of polymers has been re-examined on the basis of literature data.
Related Papers (5)
Second‐Order Transition Temperatures and Related Properties of Polystyrene. I. Influence of Molecular Weight
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Brian E. Mattioni,Peter C. Jurs +1 more