Journal ArticleDOI
Preference for photodissociation over internal [2 + 2]-cycloaddition during irradiation of an unsaturated α,β-enone
E. J. Corey,Laurence I. Wu +1 more
TLDR
In this article, it was shown that irradiation of 2, its trimethylsilyl ether or acetate ester using ultraviolet light of wavelength > 290 nm results not in internal olefin cycloaddition, but exclusively in photodissociation either of the intercyclic bond (for 2 or the TMS ether) or the COAc bond for the acetates ester.About:
This article is published in Tetrahedron Letters.The article was published on 1994-01-01. It has received 11 citations till now. The article focuses on the topics: Ultraviolet light & Cycloaddition.read more
Citations
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Journal ArticleDOI
Cyclohexadienone ketals and quinols: four building blocks potentially useful for enantioselective synthesis.
Journal ArticleDOI
Biocatalytic approaches towards the stereoselective synthesis of vicinal amino alcohols
Pankaj Gupta,Neha Mahajan +1 more
TL;DR: This comprehensive report seeks to provide an overview of recent (chemo)enzymatic methods, focusing on the strategy employed (use of transaminases, kinetic resolution, dynamic kineticresolution, biocatalytic C–C bond formation or enantioconvergent processes) and the type ofBiocatalyst(s) used for the preparation of enantiopure vicinal amino alcohols.
Journal ArticleDOI
Enantioselective Synthesis of the Ricciocarpins A and B
Journal ArticleDOI
Cyclic trans-β-amino alcohols: preparation and enzymatic kinetic resolution
TL;DR: In this article, enantioenriched cyclic β-amino alcohols, trans-2-aminocyclohexanols (ee, > 99%), trans 2-aminocylopentanols, trans 1amino-2indanols and trans 2amino 1-indanol were obtained via an Arthrobacter sp.
Journal Article
Enantioselective Synthesis of the Ricciocarpins A and B This work was supported by the Deutsche Forschungsgemeinschaft (Graduierten-Kolleg "Struktur-Eigenschafts-Beziehungen bei Heterocyclen") and the Fonds der Chemischen Industrie. We thank Prof. Dr. A. Fürstner, MPI Mülheim, for a sample of catalyst 9.
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