Journal ArticleDOI
Rate coefficients for the reaction of OH with Cl2, Br2, and I2 from 235 to 354 K
Mary K. Gilles,Mary K. Gilles,James B. Burkholder,James B. Burkholder,A. R. Ravishankara,A. R. Ravishankara +5 more
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This article is published in International Journal of Chemical Kinetics.The article was published on 1999-01-01. It has received 30 citations till now.read more
Citations
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Journal ArticleDOI
An Experimental and Theoretical Study of the Reactions OIO + NO and OIO + OH
TL;DR: In this paper, the authors investigated the kinetics of the OIO + NO reaction and showed that the reactants form a weakly bound OIONO intermediate, which then dissociates to the products IO + NO2 and HOIO2 by Rice-Ramsberger-Kassel-Markus (RRKM) calculations.
Journal ArticleDOI
Temperature-Dependent Kinetics of the Gas-Phase Reactions of OH with Cl2, CH4, and C3H8
TL;DR: In this article, the reactions of OH with molecular chlorine, methane, and propane were studied experimentally using a pulsed laser photolysis/pulsed-laser-induced fluorescence.
Journal ArticleDOI
Kinetics of the gas-phase reaction of OH with HCl.
TL;DR: A temperature dependence of the rate coefficient of the Cl + H2O --> HCl + OH reaction has been derived on the basis of the experimental data, modeling, and thermochemical information.
Journal ArticleDOI
Gas-phase OH radical-initiated oxidation of the 3-halopropenes studied by PLP-LIF in the temperature range 228–388 K
TL;DR: In this article, the absolute rate coefficients for the reactions of OH radical (k OH ) with 3-fluoropropene, 3-chloropropenes and 3-bromophropene were determined as a function of the total pressure and temperature.
Journal ArticleDOI
Kinetic study of the reactions of OH and OD with HBr and DBr
TL;DR: In this paper, the kinetics of the reactions of OH and OD radicals with HBr and DBr, OH+HBr (1), OD+DBr (2), OD−HBr(3), OD-DBr(4), OD•HBr→DBr, OD−DBr→HBr and OD•DBr.
References
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Chemical kinetics and photochemical data for use in stratospheric modeling
W. B. Demore,J. J. Margitan,Mario J. Molina,R. T. Watson,D. M. Golden,R. F. Hampson,Michael J. Kurylo,Carleton J. Howard,A. R. Ravishankara +8 more
TL;DR: As part of a series of evaluated sets, rate constants and photochemical cross sections compiled by the NASA Panel for Data Evaluation are provided in this article, with particular emphasis on the ozone layer and its possible perturbation by anthropogenic and natural phenomena.
Chemical kinetics and photochemical data for use in stratospheric modeling
W. B. Demore,Stanley P. Sander,D. M. Golden,R. F. Hampson,Michael J. Kurylo,Carleton J. Howard,A. R. Ravishankara,C. E. Kolb,Mario J. Molina +8 more
TL;DR: As part of a series of evaluated sets, rate constants and photochemical cross sections compiled by the NASA Panel for Data Evaluation are provided in this paper, with particular emphasis on the ozone layer and its possible perturbation by anthropogenic and natural phenomena.
Journal ArticleDOI
Kinetics and mechanism of hydroxyl radical reaction with methyl hydroperoxide
TL;DR: In this paper, the rate coefficient for the overall reaction, OH + CH{sub 3}OOH {yields} products (k{sub 1}) was measured by using {sup 18}OH and OD in place of OH.
Journal ArticleDOI
Temperature dependence of the rate constant and branching ratio for the OH+ClO reaction
TL;DR: In this article, the branching ratio for the DCl channel was found to range from 0.05 ± 0.02 at 298 K to 0.06 ± 1.2 at 210 K, and the temperature dependence of the rate constant for this minor channel was investigated between 210 and 298 K, yielding the following Arrhenius expression: (1.7 ± 0.3) × 10============ −13======
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Photodissociation of HNO3 at 193, 222, and 248 nm: Products and quantum yields
TL;DR: In this paper, the quantum yields for OH, O(3P), O(1D), and H(2S) from the photolysis of HNO3 have been determined at 248, 222, and 193 nm at 298 K.