Journal ArticleDOI
Reactions of aromatic radical anions. III. Evidence for an alkyl radical-radical anion combination mechanism for alkylation of sodium naphthalenide with alkyl halides
G. Dann Sargent,Glenn A. Lux +1 more
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This article is published in Journal of the American Chemical Society.The article was published on 1968-12-01. It has received 46 citations till now. The article focuses on the topics: Sodium naphthalenide & Alkylation.read more
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Journal ArticleDOI
Single electron transfer in radical ion and radical-mediated organic, materials and polymer synthesis.
TL;DR: The mechanisms and the applications in organic synthesis, materials, supramolecular, and polymer synthesis of most organic reactions mediated by single electron transfer are discussed, even though both biology and radical chemistry rely extensively on one-electron transfer processes.
Journal ArticleDOI
Electron transfer initiated reactions: bond formation and bond dissociation.
TL;DR: Electron Transfer Reactions: Fundamental Aspects and Experimental Examples 2192 3.1.
Journal ArticleDOI
Charged Carbon Nanomaterials: Redox Chemistries of Fullerenes, Carbon Nanotubes, and Graphenes
Adam J. Clancy,Adam J. Clancy,Mustafa K. Bayazit,Mustafa K. Bayazit,Stephen A. Hodge,Stephen A. Hodge,Neal T. Skipper,Christopher A. Howard,Milo S. P. Shaffer +8 more
TL;DR: This review focuses on the fundamental structural forms: buckminsterfullerene, single-walled carbon nanotubes, and single-layer graphene, describing the generation of their respective charged nanocarbon species, their interactions with solvents, chemical reactivity, specific (opto)electronic properties, and emerging applications.
Book ChapterDOI
Single Electron Transfer in Aliphatic Nucleophilic Substitution
TL;DR: In this article, the mechanism of the aliphatic nucleophilic substitution reaction has been described as a polar two-electron mechanism in which the nucleophile transfers two electrons to the new bond which is established to the electrophilic center.