Journal ArticleDOI
Reactions of oxygen atoms with 2-propanol and methanol
A. Kato,R J Cvetanović +1 more
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TLDR
In this article, the reaction of 2-propanol at 25 °C with oxygen atoms in the ground electronic state, O(3P), and, as a corollary, with the excited mercury atoms, Hg 6 (3P1), has been carried out.Abstract:
An investigation of the reaction of 2-propanol at 25 °C with oxygen atoms in the ground electronic state, O(3P), and, as a corollary, with the excited mercury atoms, Hg 6(3P1), has been carried out. The reaction of oxygen atoms with methanol at 25 °C has also been briefly studied. The general mechanism of reaction of O(3P) atoms with simple alcohols is discussed.read more
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A shock-tube investigation of the high-temperature oxidation of methanol
TL;DR: In this article, a 19 reaction mechanism was proposed which gives relatively good agreement between calculated and measured concentration profiles, and measured tmax-values were compared with results obtained from computer modelling of the reaction.
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Alkylation of phosphates and stability of phosphate triesters in DNA.
Pierre Bannon,Walter G. Verly +1 more
TL;DR: Experiments are presented which show that phosphate triesters resulting from the alkylation of DNA by ethyl methanesulfonate are very stable, most of them remaining intact after heating at 100°C for 90 min at pH 7.0.
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Efficient degradation method of emerging organic pollutants in marine environment using UV/periodate process: case of chlorazol black.
TL;DR: It was found that periodate (0.5mM) assisted-UV treatment of CB in seawater resulted in 13.16-fold increase in the initial degradation rate, compared to UV alone, and SDS surfactant, as an organic matter, did not affect the degradation process, making UV/IO4- a promising technique for treating seawater contaminated with EOPs.
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Chemical kinetics in the combustion processes: A detailed kinetics mechanism and its implementation
TL;DR: In this paper, the kinetics mechanism of oxidation of small molecules in the HCNO system was investigated. And the effect of turbulence on their yields and the ecological aspects of combustion processes were discussed.
Journal ArticleDOI
Rate Constants and CH3O Product Yield of the Reaction OH + CH3OH → Products
TL;DR: In this paper, the absolute rate constants and CH3O product yield for the reaction of OH radicals with methanol have been determined using a combined laser photolysis/resonance fluorescence (laser induced fluorescence) technique.