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Recent Advances in Polyoxometalate-Catalyzed Reactions

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This article is published in Chemical Reviews.The article was published on 2015-05-12. It has received 1352 citations till now.

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Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions

TL;DR: In this review, the applications of MOFs with multiple active sites in synergistic organic catalysis, photocatalysis and tandem reactions are discussed and proposed mechanisms are presented in detail.
Journal ArticleDOI

Metal–organic frameworks meet metal nanoparticles: synergistic effect for enhanced catalysis

TL;DR: An overview of significant progress in the development of MNP/MOF composites, including various preparation strategies and characterization methods as well as catalytic applications is provided, with special emphasis on synergistic effects between the two components that result in an enhanced performance in heterogeneous catalysis.
Journal ArticleDOI

Metal-Organic Frameworks as Platforms for Catalytic Applications.

TL;DR: An overview of recent developments achieved in MOF catalysis, including heterogeneousCatalysis, photocatalysis, and eletrocatalysis over MOFs and MOF-based materials, is provided.
Journal ArticleDOI

Metal-Organic Framework-Based Catalysts with Single Metal Sites.

TL;DR: This review overviews the recent developments of catalysis at single metal sites in MOF-based materials with emphasis on their structures and applications for thermocatalysis, electrocatalysis, and photocatalysis.
Journal ArticleDOI

Single-Atom Catalysts across the Periodic Table.

TL;DR: A compositional encyclopedia of SACs is provided, celebrating the 10th anniversary of the introduction of this term, and examines the coordination structures and associated properties accessed through distinct single-atom-host combinations and relate them to their main applications in thermo-, electro-, and photocatalysis.
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Journal ArticleDOI

Heterogeneous photocatalyst materials for water splitting

TL;DR: This critical review shows the basis of photocatalytic water splitting and experimental points, and surveys heterogeneous photocatalyst materials for water splitting into H2 and O2, and H2 or O2 evolution from an aqueous solution containing a sacrificial reagent.
Journal ArticleDOI

In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co2+

TL;DR: A catalyst that forms upon the oxidative polarization of an inert indium tin oxide electrode in phosphate-buffered water containing cobalt (II) ions is reported that not only forms in situ from earth-abundant materials but also operates in neutral water under ambient conditions.
Book

Heteropoly and Isopoly Oxometalates

TL;DR: A survey of polyoxometalates can be found in this paper, where the authors survey the chemistry, structures, and applications of these species, as well as their applications in inorganic chemistry.
Journal ArticleDOI

Bond Dissociation Energies of Organic Molecules

TL;DR: In this paper, a list of reliable bond energies that are based on a set of critically evaluated experiments is provided and a brief description of the three most important experimental techniques for measuring bond energies is provided.
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