Journal ArticleDOI
Recent advances on N-heterocyclic carbene transition metal complexes for dehydrogenative catalysis using alcohols
TLDR
A brief overview of recent advances on NHC-TM complexes for dehydrogenative catalysis using alcohols can be found in this article, where N-heterocyclic carbenes (NHCs) are green and versatile ligands for the development of transition metal catalysts.About:
This article is published in Catalysis Today.The article was published on 2021-06-15. It has received 24 citations till now. The article focuses on the topics: Carbene & Catalysis.read more
Citations
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Electronically tuneable orthometalated Ru<sup>II</sup>–NHC complexes as efficient catalysts for C–C and C–N bond formations <i>via</i> borrowing hydrogen strategy
TL;DR: A series of simple and electronically tuneable cyclometalated Ru II -NHC complexes have been explored as efficient catalysts for various C-C/N bond forming reactions via a BH methodology as mentioned in this paper .
Journal ArticleDOI
Electronically Tuneable Orthometalated RuII-NHC Complexes as Efficient Catalysts for the C-C and C-N Bond Formations via Borrowing Hydrogen Strategy
TL;DR: In this paper, the catalytic activities of a series of simple and electronically tuneable cyclometalated RuII-NHC complexes (2a-d) were explored in various C-C/N bond formations following the borrowing hydrogen process.
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Gram-scale synthesis of carboxylic acids via catalytic acceptorless dehydrogenative coupling of alcohols and hydroxides at an ultralow Ru loading
None sessd,Zhe Wu,Zhi-Qin Wang,Michael Schabacker,Hua Cheng,Zhong-Hui Zheng,Ye Yuan,Cheng Chen,Francis Verpoort,Francis Verpoort,Francis Verpoort +10 more
TL;DR: In this paper, a series of cyclometallated N-heterocyclic carbene-Ru (NHC-Ru) complexes via ligand tuning of [Ru-1], the superior complex in our previous work, were designed and fabricated.
Journal ArticleDOI
Gram-scale synthesis of carboxylic acids via catalytic acceptorless dehydrogenative coupling of alcohols and hydroxides at an ultralow Ru loading
None sessd,Michael Schabacker +1 more
TL;DR: In this article , a series of cyclometallated N-heterocyclic carbene-Ru (NHC-Ru) complexes via ligand tuning of [Ru-1], the superior complex in our previous work, were designed and fabricated.
Journal ArticleDOI
Synthesis, Crystal structures, DFT calculations, and catalytic application in Hydrosilylation of acetophenone derivatives with triethylsilane of novel rhoduim-N-heterocyclic carbene (NHCs) complex
S. Hassen,Mohamed Oussama Zouaghi,Ichraf Slimani,Youssef Arfaoui,NamıkÖzdemir,İsmail Özdemir,Nevin Gürbüz,Lamjed Mansour,Naceur Hamdi +8 more
TL;DR: In this paper , a new rhodium-based N-heterocyclic carbene complex was developed that incorporated an NHC ligand and the solid-state single-crystal X-ray structure of the complex was discussed.
References
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Applications of acceptorless dehydrogenation and related transformations in chemical synthesis.
TL;DR: Acceptorless dehydrogenation and related dehydrogenative coupling reactions have the potential for redirecting synthetic strategies to the use of sustainable resources, devoid of toxic reagents and deleterious side reactions, with no waste generation.
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Smart N-Heterocyclic Carbene Ligands in Catalysis
TL;DR: This review is to comprehensively describe all types of smart NHC ligands by focusing attention on the catalytically relevant ligand-based reactivity.
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Cyclic (alkyl)(amino)carbenes (CAACs): stable carbenes on the rise.
TL;DR: This Account discusses another class of stable cyclic carbenes, namely, cyclic (alkyl)(amino)carbenes (CAACs), and shows that the peculiar electronic and steric properties of CAACs allow for the stabilization of unusual diamagnetic and paramagnetic main group element species.
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Advances in One-Pot Synthesis through Borrowing Hydrogen Catalysis
TL;DR: The objective of the present review is to give a global overview on the topic starting from those contributions published prior to the emergence of the BH concept to the most recent and current research under the term of BH catalysis.
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3d-Metal Catalyzed N- and C-Alkylation Reactions via Borrowing Hydrogen or Hydrogen Autotransfer
Torsten Irrgang,Rhett Kempe +1 more
TL;DR: The findings in this field are expected to inspire others to develop new efficient and selective earth-abundant metal catalysts for borrowing hydrogen or hydrogen autotransfer applications or to develop novel alcohol refunctionalization reactions that can be mediated by such metals.