Recent Progress of Metal Nanoparticle Catalysts for C–C Bond Forming Reactions
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In this article, the authors classified and outlined the categories of transition metal NPs by the type of support, such as inorganic materials, magnetically recoverable materials, porous materials, organic-inorganic composites, carbon materials, polymers, and surfactants.Abstract:
Over the past few decades, the use of transition metal nanoparticles (NPs) in catalysis has attracted much attention and their use in C–C bond forming reactions constitutes one of their most important applications. A huge variety of metal NPs, which have showed high catalytic activity for C–C bond forming reactions, have been developed up to now. Many kinds of stabilizers, such as inorganic materials, magnetically recoverable materials, porous materials, organic–inorganic composites, carbon materials, polymers, and surfactants have been utilized to develop metal NPs catalysts. This review classified and outlined the categories of metal NPs by the type of support.read more
Citations
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Transition metal nanoparticles as nanocatalysts for Suzuki, Heck and Sonogashira cross-coupling reactions
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TL;DR: In this paper , the authors highlight the importance of transition metal nanoparticles in the field of selective carbon-carbon bond-forming reactions such as Suzuki, Heck, and Sonogashira coupling reactions.
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References
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Formation of self-assembled multi-layer stable palladium nanoparticles for ligand-free coupling reactions
Mitsuhiro Arisawa,Mitsuhiro Arisawa,Mohammad Al-Amin,Tetsuo Honma,Yusuke Tamenori,Satoshi Arai,Naoyuki Hoshiya,Takatoshi Sato,Mami Yokoyama,Akira Ishii,Masaki Takeguchi,Tsuyoshi Miyazaki,Takeuchi Masashi,Tomohiro Maruko,Satoshi Shuto +14 more
TL;DR: In this paper, the structure of a recently developed Pd catalyst, named sulfur-modified gold-supported palladium (SAPd), has been determined to be composed of multi-layered Pd nanoparticles.
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Multifunctional catalysts based on palladium nanoparticles supported on functionalized halloysites: Applications in catalytic C-C coupling, selective oxidation and dehalogenation reactions
Miguel Díaz-Sánchez,Miguel Díaz-Sánchez,I. Jénnifer Gómez,Sanjiv Prashar,Michal Horáček,Martin Lamač,Béla Urbán,Jiří Pinkas,Santiago Gómez-Ruiz +8 more
TL;DR: In this paper, a series of hybrid catalysts of the type, support-ligand-Pd (Sup-L-PD), has been prepared and characterized and their activity in C-C coupling (Suzuki-Miyaura), selective oxidations and dehalogenation-hydrogenation processes studied.
Journal ArticleDOI
Suzuki-Miyaura Cross-Coupling of Bromotryptophan Derivatives at Ambient Temperature.
Steffen Dachwitz,Dario H. Duwe,Yating Hong Wang,Hendrik Gruß,Yvonne Hannappel,Thomas Hellweg,Norbert Sewald +6 more
TL;DR: Ligand‐free solvent‐stabilised Pd‐nanoparticles represent an efficient and sustainable alternative to conventional phosphine‐based catalysts, because the cross‐coupling can be performed at considerably lower temperature and the results are even more efficient than the literature‐known ADHP‐Pd precatalyst.
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Palladium nanoparticles decorated on reduced graphene oxide: An efficient catalyst for ligand‐ and copper‐free Sonogashira reaction at room temperature
Abhijit Mahanta,Najrul Hussain,Najrul Hussain,Manash R. Das,Manash R. Das,Ashim Jyoti Thakur,Utpal Bora +6 more
TL;DR: In this article, a room temperature copper-free Sonagashira cross-coupling reaction in ethanol, catalysed by palladium nanoparticles homogeneously deposited on reduced graphene oxide, is presented.
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SBA-15@adenine–Pd: a novel and green heterogeneous nanocatalyst in Suzuki and Stille reactions and synthesis of sulfides
TL;DR: In this paper, anchored palladium onto the surface of organically modified mesoporous silica was successfully prepared via simple and inexpensive procedure, and the prepared nanocatalyst was considered as robust and clean nano-reactor catalyst for Suzuki and Stille reactions and synthesis of sulfide.