Recent Progress of Metal Nanoparticle Catalysts for C–C Bond Forming Reactions
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In this article, the authors classified and outlined the categories of transition metal NPs by the type of support, such as inorganic materials, magnetically recoverable materials, porous materials, organic-inorganic composites, carbon materials, polymers, and surfactants.Abstract:
Over the past few decades, the use of transition metal nanoparticles (NPs) in catalysis has attracted much attention and their use in C–C bond forming reactions constitutes one of their most important applications. A huge variety of metal NPs, which have showed high catalytic activity for C–C bond forming reactions, have been developed up to now. Many kinds of stabilizers, such as inorganic materials, magnetically recoverable materials, porous materials, organic–inorganic composites, carbon materials, polymers, and surfactants have been utilized to develop metal NPs catalysts. This review classified and outlined the categories of metal NPs by the type of support.read more
Citations
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Transition metal nanoparticles as nanocatalysts for Suzuki, Heck and Sonogashira cross-coupling reactions
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References
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Asymmetric 1,4‐Addition of Arylboronic Acids to β,γ‐Unsaturated α‐Ketoesters using Heterogeneous Chiral Metal Nanoparticle Systems
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Direct C–H bond activation: palladium-on-carbon as a reusable heterogeneous catalyst for C-2 arylation of indoles with arylboronic acids
Prantika Bhattacharjee,Purna K. Boruah,Purna K. Boruah,Manash R. Das,Manash R. Das,Utpal Bora +5 more
TL;DR: In this paper, a C(sp2)-H bond functionalization of indoles with arylboronic acids is achieved using palladium supported on carbon as a reusable heterogeneous catalyst in the presence of an oxidant under mild conditions.
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Self-Assembled Multilayer Iron(0) Nanoparticle Catalyst for Ligand-Free Carbon-Carbon/Carbon-Nitrogen Bond-Forming Reactions.
Toshiki Akiyama,Yuki Wada,Makito Yamada,Yasunori Shio,Tetsuo Honma,Shuhei Shimoda,Kazuki Tsuruta,Yusuke Tamenori,Hitoshi Haneoka,Takeyuki Suzuki,Kazuo Harada,Hayato Tsurugi,Kazushi Mashima,Jun-ya Hasegawa,Yoshihiro Sato,Mitsuhiro Arisawa +15 more
TL;DR: SAFe(0) was successfully prepared using a well-established metal-nanoparticle catalyst preparative protocol by simultaneous in situ metal NP and nanospace organization (PSSO) with 1,4-bis(trimethylsilyl)-1, 4-dihydropyrazine (Si-DHP) as a strong reducing agent.
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An efficient and new protocol for the Heck reaction using palladium nanoparticle‐engineered dibenzo‐18‐crown‐6‐ether/MCM‐41 nanocomposite in water
Maedeh Azaroon,Ali Reza Kiasat +1 more
TL;DR: Palladium nanoparticle-incorporated mesoporous organosilica (MCM-41-Crown) was synthesized via grafting of dibenzo-18-crown-6-ether moieties on the MCM41 surface, followed by reaction of the nanocomposite with palladium acetate and then its reduction in ethanol.
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Palladium Nanoparticles Supported on Graphene Oxide as Catalysts for the Synthesis of Diarylketones
Anna M. Trzeciak,Przemysław Wójcik,Radosław Lisiecki,Yuriy Gerasymchuk,Wieslaw Strek,Janina Legendziewicz +5 more
TL;DR: In this article, three palladium catalysts supported on graphene oxide (GO) and on its composite with TiO2 (GO-TiO2) were prepared and characterized, and the presence of Pd NPs of different diameters and size distributions was evidenced by TEM measurements.